Table 2.

Scale-up of mechanochemical CuAAC.

Entry	Octyl Azide (1a)		Yield a
	mmol	g	%	g
1 b	1	0.1552	99	0.254
2 b	10	1.5524	98	2.519
3 c	50	7.7620	95	12.208

^a: Isolated yield; ^b: 1 eq Cu powder, 5 min, 650 rpm; 50 mL jar, 1500 small balls (Ø = 2 mm) and 48 medium balls (Ø = 5 mm); ^c: 1 eq Cu powder, 5 min, 650 rpm; 250 mL jar, 48 medium balls (Ø = 5 mm) and 10 very large balls (Ø = 30 mm).