Table 3.
DLS results of PPI, SSPS, and complex emulsions before and after long-term storage in pH 6 with 0.2 M NaCl at 4 °C.
Sample | SDS Concentration after Dilution (%) a | Dh (nm) | PDI | |
---|---|---|---|---|
SSPS | fresh | 0 | 724 ± 12 | 0.62 ± 0.08 |
after 2 weeks | 0 | 752 ± 23 | 1.0 | |
0.3 | 699 ± 17 | 0.27 ± 0.09 | ||
PPI1 | cannot produce homogeneous emulsion | |||
PPI2 | fresh | 0 | 1094 ± 21 | 0.26 ± 0.05 |
after 1 weeks | 0 | 9025 ± 1008 | 1.0 | |
0.3 | 798 ± 17 | 0.77 ± 0.04 | ||
PPI3 | fresh | 0 | 1138 ± 15 | 0.13 ± 0.05 |
after 2 weeks | 0 | 8774 ± 198 | 1.0 | |
0.3 | 736 ± 28 | 0.81 ± 0.02 | ||
PPI4 | cannot produce homogeneous emulsion | |||
Complex1 | fresh | 0 | 319 ± 8 | 0.27 ± 0.09 |
after12 months | 0 | 426 ± 26 | 0.14 ± 0.10 | |
0.3 | 371 ± 20 | 0.16 ± 0.03 | ||
Complex2 | fresh | 0 | 283 ± 7 | 0.16 ± 0.05 |
after 14 months | 0 | 331 ± 24 | 0.12 ± 0.02 | |
0.3 | 312 ± 12 | 0.16 ± 0.02 | ||
Complex3 | fresh | 0 | 325 ± 6 | 0.23 ± 0.06 |
after 12 months | 0 | 421 ± 28 | 0.25 ± 0.10 | |
0.3 | 388 ± 2 | 0.24 ± 0.13 | ||
Complex3 (unheated) | fresh | 0 | 740 ± 70 | 0.74 ± 0.26 |
after 12 months | 0 | 3374 ± 245 | 1.0 | |
0.3 | 404 ± 50 | 0.60 ± 0.17 | ||
Complex4 | fresh | 0 | 328 ± 27 | 0.20 ± 0.03 |
after 11 months | 0 | 482 ± 178 | 0.31 ± 0.14 | |
0.3 | 404 ± 118 | 0.22 ± 0.09 |
a The DLS samples were prepared by diluting 5 μL of the creaming layer with 3 mL of solution containing the same pH and NaCl concentration as well as 0 or 0.3% SDS.