Table 1.
The composition of the essential oils of Achillea species. AB: A. biebersteinii, AC: A. coarctata, AH: A. hamzaoglui, AK: A. kotschyi subsp. kotschyi, AL: A. lycaonica, AM: A. millefolium subsp. millefolium, ASc: A. schischkinii, ASe: A. setacea, ASi: A. sintenisii, AV: A. vermicularis, and AW: A. wilhelmsii subsp. wilhelmsii.
| No | RRI a | Compound | Content b % | IM c | ||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| AB | AC | AH | AK | AL | AM | ASc | ASe | ASi | AV | AW | ||||
| 1 | 1014 | Tricyclene | 0.1 | - | - | - | - | - | - | - | - | - | 0.2 | MS |
| 2 | 1032 | α-Pinene | 1.2 | 0.6 | 0.5 | 1.0 | - | tr | 0.2 | - | - | - | 0.5 | RRI, MS |
| 3 | 1035 | α-Thujene | - | - | 0.2 | - | - | - | - | - | - | - | - | MS |
| 4 | 1043 | Santolinatriene | 0.5 | - | - | - | - | - | - | - | - | - | - | MS |
| 5 | 1076 | Camphene | 1.7 | 0.7 | 0.7 | 0.5 | - | 0.1 | tr | - | - | - | 6.1 | RRI, MS |
| 6 | 1118 | β-Pinene | 0.6 | 0.6 | 1.1 | 1.4 | - | 0.1 | 0.3 | - | - | - | 0.5 | RRI, MS |
| 7 | 1132 | Sabinene | - | - | 4.0 | - | - | 0.1 | 0.3 | - | - | - | - | RRI, MS |
| 8 | 1188 | α-Terpinene | - | - | 0.5 | 0.7 | - | 0.2 | 0.1 | - | - | - | - | RRI, MS |
| 9 | 1195 | Dehydro-1,8-cineole | - | - | 0.1 | - | - | - | - | - | - | - | - | MS |
| 10 | 1202 | 3-Hexanol | - | - | - | - | 0.4 | - | - | - | - | - | - | MS |
| 11 | 1203 | Limonene | 0.2 | - | 0.1 | 0.5 | - | - | 0.1 | - | - | - | - | RRI, MS |
| 12 | 1213 | 1,8-Cineole | 16.5 | 1.0 | 24.1 | 22.5 | 0.2 | 4.1 | 3.4 | 3.1 | 0.6 | - | 4.2 | RRI, MS |
| 13 | 1222 | 2-Hexanol | - | - | - | - | 0.2 | - | - | - | - | - | - | MS |
| 14 | 1255 | γ-Terpinene | 0.1 | - | 1.0 | 1.8 | - | 0.6 | 0.4 | - | - | - | - | RRI, MS |
| 15 | 1280 | p-Cymene | 18.6 | 0.6 | 0.2 | 8.4 | - | 1.4 | 8.5 | - | - | - | 1.8 | RRI, MS |
| 16 | 1285 | Isoamylisovalerate | - | - | 0.3 | - | - | - | - | - | - | - | 0.3 | MS |
| 17 | 1290 | Terpinolene | - | - | 0.2 | - | - | - | - | - | - | - | - | RRI, MS |
| 18 | 1294 | 1,2,4-Trimethyl benzene | 0.2 | - | - | - | - | - | - | - | - | - | - | MS |
| 19 | 1299 | 2-Methylbutyl isovalerate | - | - | - | - | - | - | - | - | - | - | 0.2 | MS |
| 20 | 1355 | 1,2,3-Trimethyl benzene | 0.2 | - | - | - | - | - | - | - | - | - | - | MS |
| 21 | 1400 | Nonanal | - | - | - | - | - | - | 0.1 | - | - | - | - | MS |
| 22 | 1400 | Tetradecane | - | - | - | - | - | - | - | - | - | 0.1 | - | RRI, MS |
| 23 | 1405 | Santolina alcohol | 1.5 | - | - | - | - | - | - | - | - | - | - | MS |
| 24 | 1445 | Filifolone | 0.3 | - | - | - | - | - | 0.1 | - | - | - | - | MS |
| 25 | 1474 | trans-Sabinene hydrate | - | - | 2.1 | 0.5 | - | 0.5 | 0.5 | - | - | - | 0.3 | MS |
| 26 | 1495 | Bicycloelemene | - | - | - | - | - | - | 0.5 | - | - | - | - | MS |
| 27 | 1497 | α-Copaene | - | - | 0.4 | - | - | - | 0.4 | - | - | - | - | MS |
| 28 | 1499 | α-Campholene aldehyde | 0.3 | - | - | - | - | - | - | - | - | - | - | RRI, MS |
| 29 | 1506 | Decanal | - | - | - | - | - | - | 0.1 | - | - | - | - | RRI, MS |
| 30 | 1522 | Chrysanthenone | 1.3 | - | - | - | - | - | - | - | - | - | - | MS |
| 31 | 1532 | Camphor | 11.7 | 9.8 | 6.7 | 2.8 | 1.7 | 4.0 | 1.5 | 4.1 | 0.5 | 6.7 | 41.3 | RRI, MS |
| 32 | 1540 | Modhephene | - | - | - | 0.4 | - | - | - | - | - | - | - | MS |
| 33 | 1547 | Dihydroachillene | 0.3 | - | - | - | - | - | - | - | - | - | 0.2 | MS |
| 34 | 1553 | Linalool | 2.1 | - | 12.2 | - | - | 0.6 | 0.5 | - | - | - | - | RRI, MS |
| 35 | 1556 | cis-Sabinene hydrate | - | - | 1.6 | - | 0.4 | 0.4 | 0.3 | - | - | - | 0.3 | MS |
| 36 | 1571 | trans-p-Menth-2-en-1-ol | 0.4 | - | 0.2 | - | - | 0.3 | 0.1 | - | - | - | - | MS |
| 37 | 1582 | cis-Chrysanthenyl acetate | - | - | - | - | 2.9 | 0.5 | - | - | 0.3 | - | - | MS |
| 38 | 1586 | Pinocarvone | 0.5 | - | 0.2 | - | - | - | 0.2 | - | - | - | 0.9 | RRI, MS |
| 39 | 1591 | Bornyl acetate | 0.2 | - | - | 1.3 | - | - | - | - | - | 5.1 | 1.5 | RRI, MS |
| 40 | 1599 | Chrysanthenyl propionate | - | - | - | - | - | - | - | - | - | 0.1 | - | MS |
| 41 | 1600 | Hexadecane | - | - | - | - | 0.3 | - | - | - | - | 0.1 | - | RRI, MS |
| 42 | 1600 | β-Elemene | - | - | - | - | - | - | 0.1 | - | - | - | - | RRI, MS |
| 43 | 1611 | Terpinen-4-ol | 0.3 | 0.7 | 3.4 | 1.2 | 0.6 | 2.4 | - | tr | - | - | 0.6 | RRI, MS |
| 44 | 1612 | β-Caryophyllene | - | - | 1.5 | - | - | - | 2.8 | - | - | - | - | RRI, MS |
| 45 | 1617 | Lavandulyl acetate | - | - | - | - | - | 1.1 | - | 0.9 | - | 3.3 | - | RRI, MS |
| 46 | 1638 | cis-p-Menth-2-en-1-ol | 0.3 | - | 0.2 | - | - | 0.2 | 0.1 | - | - | - | - | MS |
| 47 | 1648 | Myrtenal | 0.4 | - | 0.2 | - | - | - | - | 0.9 | - | - | 0.6 | MS |
| 48 | 1651 | Sabinaketone | - | - | - | - | 0.4 | - | - | - | - | - | - | MS |
| 49 | 1655 | Isobornyl propionate | - | - | - | - | - | - | - | - | - | - | 0.2 | MS |
| 50 | 1656 | Chrysanthenylisobutyrate | - | - | - | - | - | - | - | - | - | 0.1 | - | MS |
| 51 | 1661 | Alloaromadendrene | - | 0.7 | 0.2 | - | - | - | 0.4 | - | - | - | 0.3 | MS |
| 52 | 1664 | Nonanol | - | - | - | - | - | - | 0.1 | - | - | - | - | MS |
| 53 | 1670 | trans-Pinocarveol | 0.4 | - | - | - | 0.5 | - | 0.2 | - | - | - | 0.6 | RRI, MS |
| 54 | 1678 | cis-p-Mentha-2,8-dien-1-ol | - | - | - | - | - | - | - | - | - | - | - | MS |
| 55 | 1682 | δ-Terpineol | 0.3 | - | 0.7 | 0.4 | - | 0.2 | 0.1 | - | - | - | 0.1 | MS |
| 56 | 1683 | trans-Verbenol | - | - | 1.3 | - | 0.5 | - | - | - | - | - | 0.6 | MS |
| 57 | 1686 | Lavandulol | - | - | - | - | - | 0.3 | - | - | - | - | - | RRI, MS |
| 58 | 1687 | α-Humulene | - | - | - | - | - | - | 0.4 | - | - | - | - | RRI, MS |
| 59 | 1689 | trans-piperitol | 0.3 | - | - | - | - | - | - | - | - | - | - | MS |
| 60 | 1688 | Selina-4,11-diene (=4,11-Eudesmadiene) | - | - | - | - | - | - | 0.1 | - | - | - | - | MS |
| 61 | 1695 | (E)-β-Farnesene | - | - | 0.2 | - | - | - | - | - | - | - | - | MS |
| 62 | 1700 | Heptadecane | - | - | - | - | - | - | - | - | - | 0.2 | - | RRI, MS |
| 63 | 1704 | γ-Muurolene | - | - | - | - | - | - | 0.1 | - | - | - | - | MS |
| 64 | 1704 | Myrtenyl acetate | - | - | - | - | - | - | - | 0.4 | - | - | - | MS |
| 65 | 1705 | Fragranyl acetate | - | - | - | - | - | 1.0 | - | - | - | - | - | MS |
| 66 | 1706 | α-Terpineol | 0.6 | 1.2 | 2.9 | 1.6 | - | 2.2 | 1.5 | 0.8 | - | 0.1 | 0.2 | RRI, MS |
| 67 | 1715 | Geranylformate | - | - | - | - | - | - | 0.3 | - | - | - | - | MS |
| 68 | 1719 | Borneol | 0.6 | 2.1 | 0.6 | 1.0 | 0.5 | 0.4 | 0.3 | - | 1.3 | 2.5 | 6.2 | RRI, MS |
| 69 | 1722 | Cabreuva oxide-II | - | - | - | - | - | - | 0.2 | - | - | - | - | MS |
| 70 | 1726 | Germacrene D | 0.1 | - | 6.2 | - | - | - | 0.2 | - | - | 0.1 | - | MS |
| 71 | 1733 | Neryl acetate | - | - | - | - | - | 0.3 | - | - | - | 0.6 | - | RRI, MS |
| 72 | 1740 | α-Muurolene | - | - | - | - | - | - | 0.2 | - | - | - | - | MS |
| 73 | 1742 | β-Selinene | - | - | - | - | - | - | - | 1.0 | 0.3 | - | 0.4 | MS |
| 74 | 1743 | Chrysanthenyl isovalerate I | - | - | - | - | 0.4 | - | - | - | - | 4.8 | - | ,MS |
| 75 | 1748 | Piperitone | 1.3 | - | - | - | - | - | 1.4 | - | - | - | - | RRI, MS |
| 76 | 1755 | Bicyclogermacrene | - | - | 2.8 | - | - | - | 0.2 | - | - | - | - | MS |
| 77 | 1758 | cis-Piperitol | 0.3 | - | - | 0.5 | - | 0.2 | 0.2 | - | - | - | - | MS |
| 78 | 1760 | Chrysanthenylisovalerate II | - | - | - | - | - | - | - | - | - | 3.3 | - | MS |
| 79 | 1764 | cis-Chrysanthenol | - | - | - | - | 2.9 | 1.5 | - | - | - | - | - | MS |
| 80 | 1768 | Cabreuva oxide-IV | - | - | - | - | - | - | 0.2 | - | - | - | - | MS |
| 81 | 1770 | Isobornylisovalerate | - | - | - | - | - | - | - | - | - | - | 0.6 | MS |
| 82 | 1773 | δ-Cadinene | - | - | 0.2 | - | - | 1.4 | 0.2 | - | - | - | - | MS |
| 83 | 1776 | γ-Cadinene | - | - | - | - | 0.5 | - | 0.1 | - | - | 0.1 | - | MS |
| 84 | 1783 | β-Sesquiphellandrene | - | - | - | - | - | - | - | - | - | 0.1 | - | MS |
| 85 | 1786 | ar-Curcumene | - | - | - | - | - | - | - | 0.2 | - | 1.3 | - | MS |
| 86 | 1786 | Aromadendra-1(10),4(15)-diene | - | - | - | - | - | - | 0.6 | - | - | - | - | MS |
| 87 | 1800 | Octadecane | - | - | - | - | - | - | - | - | - | 0.1 | - | RRI, MS |
| 88 | 1802 | Cumin aldehyde | 0.6 | - | - | 0.6 | - | - | 0.2 | - | - | - | - | RRI, MS |
| 89 | 1804 | Myrtenol | 0.2 | - | 0.2 | - | - | - | - | 1.7 | - | - | 0.4 | MS |
| 90 | 1807 | Fragranol | - | - | - | - | - | 2.2 | - | - | - | - | - | MS |
| 91 | 1808 | Nerol | - | - | - | - | - | 0.6 | - | - | - | - | - | RRI, MS |
| 92 | 1823 | p-Mentha-1(7),5-dien-2-ol | - | - | - | - | - | - | 0.1 | - | - | - | - | MS |
| 93 | 1830 | Tridecanal | - | - | - | - | 0.1 | - | 0.2 | - | - | - | - | MS |
| 94 | 1849 | Calamenene | - | - | - | - | - | 0.2 | - | - | - | - | - | MS |
| 95 | 1857 | Geraniol | - | - | - | - | - | - | 0.2 | - | - | - | - | RRI, MS |
| 96 | 1868 | (E)-Geranyl acetone | - | - | - | - | 0.2 | - | 0.1 | - | - | 0.1 | - | MS |
| 97 | 1898 | 1,11-Oxidocalamenene | - | - | - | - | - | 0.5 | - | - | - | - | - | MS |
| 98 | 1900 | epi-Cubebol | - | - | - | - | - | tr | - | - | - | - | MS | |
| 99 | 1900 | Nonadecane | - | - | - | - | - | - | - | - | - | 0.1 | - | RRI, MS |
| 100 | 1921 | α-Phellandrene epoxide | - | - | - | - | - | - | 0.3 | - | - | - | - | MS |
| 101 | 1941 | α-Calacorene | - | - | - | - | - | 1.1 | 0.1 | - | - | - | - | MS |
| 102 | 1945 | 1,5-Epoxy-salvial(4)14-ene | - | - | - | - | 3.9 | - | - | - | 0.4 | 1.1 | - | MS |
| 103 | 1953 | Palustrol | - | 0.8 | - | - | - | - | - | - | - | - | - | MS |
| 104 | 1957 | Cubebol | - | - | - | - | 0.3 | - | 0.1 | - | - | - | - | MS |
| 105 | 1958 | (E)-β-Ionone | - | - | - | - | - | - | - | - | - | 0.6 | - | MS |
| 106 | 1969 | cis-Jasmone | 0.5 | - | - | - | 0.3 | - | - | - | - | - | - | MS |
| 107 | 1984 | γ-Calacorene | - | - | - | - | - | 0.2 | - | - | - | - | - | MS |
| 108 | 2001 | Isocaryophyllene oxide | - | - | 0.2 | - | - | - | 0.3 | - | - | - | - | MS |
| 109 | 2008 | Caryophyllene oxide | 0.4 | 9.6 | 3.9 | 10.1 | 3.2 | 7.7 | 17.5 | 3.1 | 7.5 | 0.7 | 3.1 | RRI, MS |
| 110 | 2030 | Methyl eugenol | - | - | - | - | - | - | - | - | - | 0.1 | - | RRI, MS |
| 111 | 2037 | Salvial-4(14)-en-1-one | - | - | - | - | 1.7 | - | 0.2 | - | 0.6 | 0.4 | - | MS |
| 112 | 2041 | Pentadecanal | 0.2 | - | 0.2 | - | 1.0 | 0.3 | - | 0.5 | 0.7 | 0.7 | 0.2 | MS |
| 113 | 2050 | (E)-Nerolidol | - | - | 2.2 | 1.6 | - | 1.1 | 6.2 | - | 0.4 | 4.4 | - | MS |
| 114 | 2056 | 13-Tetradecanolide | 0.2 | - | - | - | 0.7 | - | - | 0.8 | - | - | 1.5 | MS |
| 115 | 2057 | Ledol | - | 1.6 | - | - | - | 0.5 | 0.7 | - | - | - | - | MS |
| 116 | 2071 | Humulene epoxide-II | - | 0.4 | - | 0.5 | 0.5 | 0.8 | 1.1 | - | 0.3 | - | - | MS |
| 117 | 2074 | Caryophylla-2(12),6(13)-dien-5-one | - | 0.8 | - | 0.9 | 0.2 | - | 0.5 | - | 0.6 | - | 1.8 | MS |
| 118 | 2080 | Junenol (=Eudesm-4(15)-en-6-ol) | - | - | - | - | - | - | 0.2 | - | - | - | - | MS |
| 119 | 2088 | 1-epi-Cubenol | - | - | - | - | - | 4.1 | - | - | - | - | - | MS |
| 120 | 2092 | β-Oplopenone | - | - | - | - | 0.5 | - | - | - | - | - | - | MS |
| 121 | 2104 | Viridiflorol | - | 25.9 | - | 3.9 | - | - | 0.2 | - | - | - | - | MS |
| 122 | 2130 | Salviadienol | - | - | - | - | 0.8 | - | - | - | - | - | - | MS |
| 123 | 2131 | Hexahydrofarnesyl acetone | 0.3 | - | - | 0.8 | 3.3 | 0.2 | 0.6 | 0.8 | 0.7 | 1.1 | 0.6 | MS |
| 124 | 2144 | Spathulenol | 0.5 | 1.3 | 2.0 | 2.6 | 4.6 | 2.5 | 9.1 | 2.2 | 2.7 | 3.3 | 0.4 | MS |
| 125 | 2156 | α-Bisabolol oxide B | - | - | - | - | - | 0.7 | - | 5.7 | - | - | - | MS |
| 126 | 2161 | Bisabolol oxide | - | - | - | - | - | 0.6 | - | 1.1 | - | - | - | RRI, MS |
| 127 | 2161 | Muurola-4,10(14)-dien-1-ol | - | - | - | - | - | 6.8 | 0.2 | - | - | - | - | MS |
| 128 | 2179 | 1-Tetradecanol | - | - | - | - | 0.4 | - | 0.1 | - | - | 0.7 | - | MS |
| 129 | 2185 | γ-Eudesmol | 0.1 | - | - | - | - | - | - | - | - | - | - | MS |
| 130 | 2186 | Eugenol | 0.1 | - | - | - | - | - | - | - | - | - | - | RRI, MS |
| 131 | 2187 | T-Cadinol | - | - | 0.4 | 1.0 | 1.1 | - | 1.2 | - | - | - | 0.6 | MS |
| 132 | 2191 | Zingiberenol | - | - | - | - | - | - | - | 0.4 | - | - | - | MS |
| 133 | 2198 | Thymol | 0.5 | - | - | 0.6 | - | - | 1.2 | - | - | - | 2.1 | RRI, MS |
| 134 | 2200 | α-Bisabolon oxide A | - | - | - | - | - | - | - | 27.0 | - | - | - | MS |
| 135 | 2204 | Eremoligenol | - | - | - | - | - | - | 0.8 | - | - | - | - | MS |
| 136 | 2209 | T-Muurolol | - | - | 0.3 | - | - | - | - | - | - | 0.2 | - | MS |
| 137 | 2210 | Copaborneol | - | - | - | - | 0.8 | - | - | - | - | - | - | MS |
| 138 | 2211 | Clovenol | - | 0.6 | - | - | - | - | 0.3 | - | - | - | - | MS |
| 139 | 2214 | ar-Turmerol | - | - | - | - | 0.5 | - | - | 0.6 | - | 0.8 | - | MS |
| 140 | 2221 | Isocarvacrol | 0.4 | - | - | - | - | - | - | - | - | - | - | MS |
| 141 | 2232 | α-Bisabolol | - | - | - | - | - | 11.7 | - | 4.8 | - | 0.5 | - | RRI, MS |
| 142 | 2239 | Carvacrol | 1.4 | - | - | - | - | - | 0.6 | - | - | - | 0.3 | RRI, MS |
| 143 | 2241 | Heptadecanal | - | - | - | - | 0.9 | - | - | - | - | - | - | MS |
| 144 | 2247 | trans-α-Bergamotol | - | - | - | - | - | - | 0.4 | - | - | - | - | MS |
| 145 | 2255 | α-Cadinol | - | - | - | 0.3 | - | - | - | - | - | - | - | RRI, MS |
| 146 | 2256 | Cadalene | - | - | - | - | - | 1.4 | - | - | - | - | - | MS |
| 147 | 2257 | β-Eudesmol | 10.1 | 7.4 | 1.9 | 4.9 | - | - | 3.4 | - | 26.4 | 4.4 | - | RRI, MS |
| 148 | 2260 | 15-Hexadecanolide | 0.6 | 9.4 | - | - | 2.2 | - | - | - | - | 19.6 | 0.9 | MS |
| 149 | 2264 | Intermedeol | - | - | - | 0.7 | - | - | - | - | - | - | - | MS |
| 150 | 2279 | Pentadecanol | - | - | - | - | - | - | - | 0.7 | - | - | - | MS |
| 151 | 2300 | Tricosane | 0.9 | 0.8 | - | 0.7 | 1.3 | 0.4 | 0.7 | 1.2 | 2.4 | 1.4 | 0.4 | RRI, MS |
| 152 | 2316 | Caryophylla-2(12),6(13)-dien-5β-ol (=Caryophylladienol I) | - | 0.9 | 1.0 | 0.6 | 0.1 | 0.8 | 1.5 | - | 1.6 | - | 2.3 | MS |
| 153 | 2324 | Caryophylla-2(12),6(13)-dien-5α-ol (=Caryophylladienol II) | - | 4.3 | 2.9 | 2.4 | 2.7 | 2.6 | 4.9 | 1.2 | 4.8 | - | 6.4 | MS |
| 154 | 2325 | Bisabolone | - | - | - | - | - | - | - | 0.7 | - | - | - | RRI, MS |
| 155 | 2369 | Eudesma-4(15),7-dien-4β-ol | - | - | - | - | 0.6 | 0.6 | 0.9 | - | 0.6 | 1.0 | - | MS |
| 156 | 2384 | Hexadecanol | - | - | - | - | - | - | - | 0.5 | - | 0.6 | - | MS |
| 157 | 2389 | Caryophylla-2(12),6-dien-5α-ol (=Caryophyllenol I) | - | 2.9 | - | 1.1 | 1.1 | - | 1.2 | - | 0.5 | - | 0.7 | MS |
| 158 | 2392 | Caryophylla-2(12),6-dien-5β-ol (=Caryophyllenol II) | - | 2.9 | 1.0 | 1.7 | 1.5 | 1.2 | 3.8 | - | 2.4 | - | 2.7 | MS |
| 159 | 2400 | Tetracosane | - | - | - | - | - | - | - | - | 0.5 | 0.8 | - | RRI, MS |
| 160 | 2411 | 4-Isopropyl-6-methyl-1-tetralone | - | - | - | - | - | 0.6 | - | - | - | - | - | MS |
| 161 | 2430 | Chamazulene | - | - | - | - | - | 0.4 | - | - | - | - | - | MS |
| 162 | 2438 | α-Bisabolol oxide A | - | - | - | - | - | - | - | 0.7 | - | - | - | MS |
| 163 | 2475 | 1-Heptadecanol | - | - | - | - | - | - | - | - | - | 1.0 | - | MS |
| 164 | 2500 | Pentacosane | 1.4 | 0.7 | - | 1.2 | 6.1 | 1.5 | 0.2 | 2.2 | 3.7 | 4.4 | 1.3 | RRI, MS |
| 165 | 2607 | 1-Octadecanol | - | 0.8 | - | - | 1.0 | - | - | - | 2.2 | 2.0 | 0.6 | MS |
| 166 | 2607 | Octadecanol | - | - | - | 0.5 | - | - | - | - | - | - | - | MS |
| 167 | 2622 | Phytol | - | - | - | - | 1.0 | 0.4 | - | - | - | 0.9 | - | MS |
| 168 | 2670 | Tetradecanoic acid | 0.8 | - | - | 0.7 | - | - | - | - | 1.4 | - | - | RRI, MS |
| 169 | 2676 | (Z)-Octadec-9-en-18-olide | 0.3 | - | - | - | 1.3 | - | - | - | - | - | - | MS |
| 170 | 2679 | Manool | - | - | - | - | - | - | - | - | - | 0.3 | - | MS |
| 171 | 2700 | Heptacosane | 1.0 | - | - | 1.7 | 9.2 | 1.8 | 0.7 | 1.6 | 4.1 | 6.3 | 1.1 | RRI, MS |
| 172 | 2795 | Eicosanol | - | - | - | - | - | - | - | - | 1.7 | - | - | MS |
| 173 | 2800 | Octacosane | - | - | - | - | - | - | - | - | 1.3 | - | - | RRI, MS |
| 174 | 2822 | Pentadecanoic acid | 0.4 | - | - | - | - | - | - | - | - | - | - | RRI, MS |
| 175 | 2900 | Nonacosane | 0.2 | - | - | tr | 10.6 | 2.6 | 0.4 | 1.3 | 2.6 | 4.1 | 1.1 | RRI, MS |
| 176 | 2931 | Hexadecanoic acid | 11.2 | 8.2 | - | 7.7 | - | 4.6 | 1.9 | 16.4 | 22.7 | - | 0.6 | RRI, MS |
| Monoterpene Hydrocarbones | 39.5 | 3.5 | 32.7 | 36.8 | 0.2 | 6.6 | 13.3 | 3.1 | 0.6 | - | 13.3 | |||
| Oxygenated Monoterpenes | 26.6 | 13.8 | 32.5 | 10.5 | 11 | 18.9 | 9.8 | 8.8 | 2.1 | 26.8 | 56.4 | |||
| Sesquiterpene Hydrocarbones | 0.1 | 0.7 | 11.5 | 0.4 | 0.5 | 4.3 | 6.4 | 1.2 | 0.3 | 1.6 | 0.7 | |||
| Oxygenated Sesquiterpenes | 11.1 | 59.4 | 15.8 | 32.3 | 24.1 | 42.2 | 55.4 | 47.5 | 48.8 | 16.8 | 18 | |||
| Diterpenes | - | - | - | - | 1.0 | 0.4 | - | - | 1.2 | - | ||||
| Fatty acid + esters | 12.4 | 8.2 | - | 8.4 | - | 4.6 | 1.9 | 16.4 | 24.1 | - | 0.6 | |||
| Others | 6.0 | 11.7 | 0.5 | 4.9 | 39.3 | 7.8 | 3.1 | 9.6 | 19.9 | 43.9 | 8.8 | |||
| Identified components | 55 | 28 | 45 | 41 | 48 | 57 | 82 | 31 | 30 | 46 | 46 | |||
| Total | 95.7 | 97.3 | 93.0 | 93.3 | 76.1 | 84.8 | 89.9 | 86.6 | 95.8 | 90.3 | 97.8 | |||
a Relative retention indices calculated against n-alkanes; b % calculated from TIC data. c IM: Identification method based on the relative retention indices (RRI) of authentic compounds on the HP Innowax column; MS, identified on the basis of computer matching of the mass spectra with those of the Wiley and MassFinder libraries and comparison with literature data; tr: <0.1%.