Table 3.
Entry | Time (h) | Conversion (%) | Selectivity (%) | ||||
---|---|---|---|---|---|---|---|
Benzylamine | 4-Methoxybenzylamine | P1 | P2 | P3 | P4 | ||
1 | 2 | 13 | 13 | 0 | 0 | 100 | 0 |
2 | 4 | 41 | 57 | 12 | 12 | 40 | 36 |
3 | 8 | 84 | 90 | 15 | 16 | 38 | 32 |
4 | 17 | 96 | 97 | 19 | 16 | 40 | 26 |
5 | 20 | 96 | 97 | 21 | 16 | 40 | 24 |
a Reaction Conditions: 25 mg catalyst, 0.25 mmol amine substrates, 2 mL acetonitrile, 500 W halogen lamp (cut-off wavelength below 400 nm) intensity 0.36 W/cm2, 1 atm O2.