Table 2.
Carbon | 1 a | 2 b | 3 b |
---|---|---|---|
1 | 111.3 | 111.0 | 112.3 |
2 | 153.3 | 153.5 | 156.0 |
3 | 99.7 | 99.7 c | 117.7 |
4 | 157.9 | 157.9 | 158.6 |
5 | 128.8 | 128.8 | 129.6 |
6 | 116.6 | 116.6 | 114.4 |
7 | 154.1 | 154.1 | 156.8 |
8 | 110.9 | 110.9 | 115.4 |
9 | 126.7 | 126.8 | 31.8 |
10 | 125.0 | 124.7 | 31.4 |
4a | 114.2 | 114.2 | 121.1 |
4b | 123.6 | 123.6 | 126.3 |
8a | 132.5 | 132.4 | 140.9 |
10a | 133.4 | 133.3 | 141.9 |
1′ | 110.6 | 111.0 | 110.9 |
2′ | 153.1 | 153.3 | 154.3 |
3′ | 99.0 | 99.8 c | 100.5 |
4′ | 157.7 | 157.8 | 160.5 |
5′ | 112.7 | 123.5 | 130.5 |
6′ | 145.6 | 117.4 | 117.2 |
7′ | 144.2 | 145.5 | 158.1 |
8′ | 111.7 | 140.8 | 109.5 |
9′ | 126.5 | 120.0 | 128.6 |
10′ | 121.5 | 124.7 | 126.5 |
4a′ | 113.8 | 114.2 | 116.7 |
4b′ | 124.4 | 124.3 | 126.6 |
8a′ | 125.6 | 126.2 | 134.5 |
10a′ | 133.8 | 133.4 | 135.2 |
4-OCH3 | 55.5 | 55.5 | 60.0 |
4′-OCH3 | 55.5 | 55.5 | 56.2 |
7′-OCH3 | 55.8 | ||
8′-OCH3 | 60.3 |
a 13C-NMR data were measured at 150 MHZ in DMSO-d6 for 1, δ in ppm; b 13C-NMR data were measured at 125 MHZ in DMSO-d6 for 2, in CD3OD for 3, δ in ppm, J in Hz; c the signals under the same superscript may be interchanged.