Table 4.

PC-SAFT binary interaction parameters ^a for binary sub-systems considered in this work and average relative deviations (ARDs) of calculated and experimental solubilities. All other binary parameters were set to zero.

	Binary Parameter		Temperature Range of the Experimental Data (K)	Ref for Parameters	Ref for Exp Data	ARD (%)
	kij,slope (−)	kij,int (−)
API/solvent
NA/water	9.46 × 10−5	−2.94 × 10−2	298–328	[26]	[59]	0.59
NA/acetonitrile	2.92 × 10−4	−8.46 × 10−2	288.47–309.4	[26]	this work	9.34
NA/ethanol	8.39 × 10−5	−2.10 × 10−2	293.51–318.05	[26]	this work	1.57
NA/ethyl acetate	7.68 × 10−4	−2.66 × 10−1	288.15–318.15	this work	this work	17.5
CF/solvent
SA/water	−7.30 × 10−5	−5.56 × 10−3	293.15–318.15	[26]	[26]	1.18
SA/acetonitrile	4.70 × 10−5	−2.38 × 10−1	293.15–318.15	[26]	[26]	2.65
SA/ethanol	2.63 × 10−4	−3.00 × 10−1	293.15–318.15	[26]	[26]	2.37
SA/ethyl acetate	1.53 × 10−4	−2.74 × 10−1	293.15–318.15	this work	this work	0.60
solvent/anti-solvent
ethanol/water	0	−0.0382	343	[48]	[60]
ethanol/acetonitrile	0	−0.005	293.15	[61]	[62]
ethanol/ethyl acetate	0	−0.018	344.58–350.55	[61]	[62]

^a Binary parameters should be used together with pure-component parameters from Table 2.