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. 2016 Nov 19;21(11):1576. doi: 10.3390/molecules21111576

Table 2.

Quantitative results for rosemary extract (poly)phenolic compounds.

ID. a Compounds Quantified as… Concentration (mg/mL)
1 Caffeic acid Caffeic acid b 0.03 ± 0.00
3 p-Coumaric acid Caffeic acid 0.01 ± 0.00
4 Luteolin-rutinoside Luteolin-4-glucoside 0.00 ± 0.00
5 Luteolin-hexoside Luteolin-4-glucoside 0.01 ± 0.00
6 Isorhamnetin-3-O-hexoside Rutin 0.04 ± 0.00
7 4-hydroxybenzoic acid Caffeic acid 0.01 ± 0.00
8 Apigenin-7-O-glucoside Vitexin (Apigenin-8-C-glucoside) 0.02 ± 0.00
9 Hesperidin (Hesperetin-7-O-rutinoside) Hesperidin (Hesperitin-7-rutinoside) b 0.26 ± 0.02
10 Homoplantaginin (Hispidulin 7-glucoside) Luteolin-4-glucoside 0.12 ± 0.02
11 Rosmarinic acid Rosmarinic acid b 0.12 ± 0.01
12 Luteolin-7-O-glucuronide Luteolin-4-glucoside 0.01 ± 0.00
13 Dihydroxy-dimethoxyflavone derivative Luteolin-4-glucoside 0.01 ± 0.00
14 Dihydroxy-dimethoxyflavone Luteolin-4-glucoside 0.00 ± 0.00
16 Dihydroxy-dimethoxyflavone Luteolin-4-glucoside 0.02 ± 0.00
17 Luteolin 3′-O-acetyl-O-glucuronide Luteolin-4-glucoside 0.01 ± 0.00
20 Isorhamnetin rutinoside Rutin 0.00 ± 0.00
21 Luteolin Luteolin-4-glucoside 0.14 ± 0.03
22 Isorhamnetin Rutin 0.12 ± 0.01
23 Trihydroxy-methoxyflavone Vitexin (Apigenin-8-C-glucoside) 0.18 ± 0.01
24 Methyl rosmarinate Rosmarinic acid 0.02 ± 0.00
25 Apigenin-7-O-rutinoside Vitexin (Apigenin-8-C-glucoside) 0.00 ± 0.00
26 Apigenin Vitexin (Apigenin-8-C-glucoside) 0.55 ± 0.04
27 Hispidulin-rutinoside Luteolin-4-glucoside 0.89 ± 0.15
29 5,6,7,10-tetrahydro-7-hydroxyrosmariquinone derivative Carnosol 0.27 ± 0.02
31 Carnosol methyl ether isomer Carnosol 0.00 ± 0.00
32 Rosmanol Rosmanol b 0.15 ± 0.01
33 Rosmadial isomer or rosmanolquinone Rosmanol 0.00 ± 0.00
34 Rosmanol isomer (epirosmanol) Rosmanol 0.14 ± 0.01
35 Carnosol quinone Carnosol 0.02 ± 0.00
38 Carnosic acid hexoside Carnosic acid 0.00 ± 0.00
39 Rosmanol isomer (epiisorosmanol) Rosmanol 0.06 ± 0.01
40 5,6,7,10-tetrahydro-7-hydroxyrosmariquinone derivative Carnosol 0.08 ± 0.01
41 Carnosol methyl ether isomer Carnosol 0.00 ± 0.00
42 Carnosol methyl ether isomer Carnosol 0.00 ± 0.00
43 Carnosic acid derivative Carnosic acid 0.00 ± 0.00
44 Rosmanol methyl ether Rosmanol 0.00 ± 0.00
45 Rosmadial or rosmanol quinone Rosmanol 0.89 ± 0.08
46 Epiisorosmanol methyl ether Rosmanol 0.01 ± 0.00
47 Rosmanol methyl ether isomer Rosmanol 0.00 ± 0.00
48 Carnosol Carnosol b 28.89 ± 2.24
49 Carnosic acid quinone Carnosic acid 0.17 ± 0.14
51 Rosmadial Rosmanol 1.25 ± 0.07
52 Rosmaridiphenol Carnosol 0.57 ± 0.04
53 5,6,7,10-tetrahydro-7-hydroxyrosmariquinone Carnosol 0.01 ± 0.00
54 Carnosic acid Carnosic acid b 121.08 ± 7.67
55 12-O-Methylcarnosic acid 12-O-Methylcarnosic acid 6.90 ± 0.58
56 Carnosol isomer Carnosol b 1.16 ± 0.07
57 Betulinic acid Betulinic acid b 2.10 ± 0.25
Hydroxybenzoic acids c 0.01 ± 0.00
Hydroxycinnamic acids d 0.04 ± 0.00
Rosmarinic acid derivatives e 0.14 ± 0.01
Flavones f 1.82 ± 0.18
Flavonols g 0.31 ± 0.02
Flavanones h 0.26 ± 0.02
Carnosic acid derivatives i 128.15 ± 8.11
Carnosol derivatives j 30.08 ± 2.31
Rosmanol derivatives k 1.25 ± 0.11
Other diterpene derivatives l 2.18 ± 0.12
Triterpenic acids m 2.10 ± 0.25
Total phenolics 166.32 ± 11.05

a See Table 1 for peak assignment; b Quantified by comparison with its corresponding standard; c Hydroxybenzoic acids include compound 7; d Hydroxycinnamic acids, compounds 1 and 3; e Rosmarinic acid derivatives, compounds 11 and 24; f Flavones, compounds 4, 5, 8, 10, 1214, 16, 17, 23, and 2527; g Flavonols, compounds 6 and 2022; h Flavanones, compound 9; i Carnosic acid derivatives, compounds 38, 43, 49, 54, and 55; j Carnosol derivatives, compounds 31, 35, 41, 42, 48, and 56; k Rosmanol derivatives, compounds 3234, 39, and 4447; l Other diterpene derivatives, compounds 29, 40, and 5153; and m Triterpenic acids, compound 57. Mean (n = 3) ± standard deviation(SD).