Table 2.
ID. a | Compounds | Quantified as… | Concentration (mg/mL) | ||
---|---|---|---|---|---|
1 | Caffeic acid | Caffeic acid b | 0.03 | ± | 0.00 |
3 | p-Coumaric acid | Caffeic acid | 0.01 | ± | 0.00 |
4 | Luteolin-rutinoside | Luteolin-4-glucoside | 0.00 | ± | 0.00 |
5 | Luteolin-hexoside | Luteolin-4-glucoside | 0.01 | ± | 0.00 |
6 | Isorhamnetin-3-O-hexoside | Rutin | 0.04 | ± | 0.00 |
7 | 4-hydroxybenzoic acid | Caffeic acid | 0.01 | ± | 0.00 |
8 | Apigenin-7-O-glucoside | Vitexin (Apigenin-8-C-glucoside) | 0.02 | ± | 0.00 |
9 | Hesperidin (Hesperetin-7-O-rutinoside) | Hesperidin (Hesperitin-7-rutinoside) b | 0.26 | ± | 0.02 |
10 | Homoplantaginin (Hispidulin 7-glucoside) | Luteolin-4-glucoside | 0.12 | ± | 0.02 |
11 | Rosmarinic acid | Rosmarinic acid b | 0.12 | ± | 0.01 |
12 | Luteolin-7-O-glucuronide | Luteolin-4-glucoside | 0.01 | ± | 0.00 |
13 | Dihydroxy-dimethoxyflavone derivative | Luteolin-4-glucoside | 0.01 | ± | 0.00 |
14 | Dihydroxy-dimethoxyflavone | Luteolin-4-glucoside | 0.00 | ± | 0.00 |
16 | Dihydroxy-dimethoxyflavone | Luteolin-4-glucoside | 0.02 | ± | 0.00 |
17 | Luteolin 3′-O-acetyl-O-glucuronide | Luteolin-4-glucoside | 0.01 | ± | 0.00 |
20 | Isorhamnetin rutinoside | Rutin | 0.00 | ± | 0.00 |
21 | Luteolin | Luteolin-4-glucoside | 0.14 | ± | 0.03 |
22 | Isorhamnetin | Rutin | 0.12 | ± | 0.01 |
23 | Trihydroxy-methoxyflavone | Vitexin (Apigenin-8-C-glucoside) | 0.18 | ± | 0.01 |
24 | Methyl rosmarinate | Rosmarinic acid | 0.02 | ± | 0.00 |
25 | Apigenin-7-O-rutinoside | Vitexin (Apigenin-8-C-glucoside) | 0.00 | ± | 0.00 |
26 | Apigenin | Vitexin (Apigenin-8-C-glucoside) | 0.55 | ± | 0.04 |
27 | Hispidulin-rutinoside | Luteolin-4-glucoside | 0.89 | ± | 0.15 |
29 | 5,6,7,10-tetrahydro-7-hydroxyrosmariquinone derivative | Carnosol | 0.27 | ± | 0.02 |
31 | Carnosol methyl ether isomer | Carnosol | 0.00 | ± | 0.00 |
32 | Rosmanol | Rosmanol b | 0.15 | ± | 0.01 |
33 | Rosmadial isomer or rosmanolquinone | Rosmanol | 0.00 | ± | 0.00 |
34 | Rosmanol isomer (epirosmanol) | Rosmanol | 0.14 | ± | 0.01 |
35 | Carnosol quinone | Carnosol | 0.02 | ± | 0.00 |
38 | Carnosic acid hexoside | Carnosic acid | 0.00 | ± | 0.00 |
39 | Rosmanol isomer (epiisorosmanol) | Rosmanol | 0.06 | ± | 0.01 |
40 | 5,6,7,10-tetrahydro-7-hydroxyrosmariquinone derivative | Carnosol | 0.08 | ± | 0.01 |
41 | Carnosol methyl ether isomer | Carnosol | 0.00 | ± | 0.00 |
42 | Carnosol methyl ether isomer | Carnosol | 0.00 | ± | 0.00 |
43 | Carnosic acid derivative | Carnosic acid | 0.00 | ± | 0.00 |
44 | Rosmanol methyl ether | Rosmanol | 0.00 | ± | 0.00 |
45 | Rosmadial or rosmanol quinone | Rosmanol | 0.89 | ± | 0.08 |
46 | Epiisorosmanol methyl ether | Rosmanol | 0.01 | ± | 0.00 |
47 | Rosmanol methyl ether isomer | Rosmanol | 0.00 | ± | 0.00 |
48 | Carnosol | Carnosol b | 28.89 | ± | 2.24 |
49 | Carnosic acid quinone | Carnosic acid | 0.17 | ± | 0.14 |
51 | Rosmadial | Rosmanol | 1.25 | ± | 0.07 |
52 | Rosmaridiphenol | Carnosol | 0.57 | ± | 0.04 |
53 | 5,6,7,10-tetrahydro-7-hydroxyrosmariquinone | Carnosol | 0.01 | ± | 0.00 |
54 | Carnosic acid | Carnosic acid b | 121.08 | ± | 7.67 |
55 | 12-O-Methylcarnosic acid | 12-O-Methylcarnosic acid | 6.90 | ± | 0.58 |
56 | Carnosol isomer | Carnosol b | 1.16 | ± | 0.07 |
57 | Betulinic acid | Betulinic acid b | 2.10 | ± | 0.25 |
Hydroxybenzoic acids c | 0.01 | ± | 0.00 | ||
Hydroxycinnamic acids d | 0.04 | ± | 0.00 | ||
Rosmarinic acid derivatives e | 0.14 | ± | 0.01 | ||
Flavones f | 1.82 | ± | 0.18 | ||
Flavonols g | 0.31 | ± | 0.02 | ||
Flavanones h | 0.26 | ± | 0.02 | ||
Carnosic acid derivatives i | 128.15 | ± | 8.11 | ||
Carnosol derivatives j | 30.08 | ± | 2.31 | ||
Rosmanol derivatives k | 1.25 | ± | 0.11 | ||
Other diterpene derivatives l | 2.18 | ± | 0.12 | ||
Triterpenic acids m | 2.10 | ± | 0.25 | ||
Total phenolics | 166.32 | ± | 11.05 |
a See Table 1 for peak assignment; b Quantified by comparison with its corresponding standard; c Hydroxybenzoic acids include compound 7; d Hydroxycinnamic acids, compounds 1 and 3; e Rosmarinic acid derivatives, compounds 11 and 24; f Flavones, compounds 4, 5, 8, 10, 12–14, 16, 17, 23, and 25–27; g Flavonols, compounds 6 and 20–22; h Flavanones, compound 9; i Carnosic acid derivatives, compounds 38, 43, 49, 54, and 55; j Carnosol derivatives, compounds 31, 35, 41, 42, 48, and 56; k Rosmanol derivatives, compounds 32–34, 39, and 44–47; l Other diterpene derivatives, compounds 29, 40, and 51–53; and m Triterpenic acids, compound 57. Mean (n = 3) ± standard deviation(SD).