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. 2016 Mar 2;21(3):294. doi: 10.3390/molecules21030294
Hirtusneanine (DMSO-d6)
Position δC δH (J in Hz)
1 159.2 -
–OH 1 - 11.5 (br s) (1H)
2 116.7 -
3 149.6 -
4 109.2 6.66 (s) (1H)
4a 156.8
5 68.8 4.02 (d, 9.5) (1H)
6 31.3 2.05 (ddq, 10.3, 9.5, 6.7) (1H)
7 36.7 2.36 (dq, 10.3, 6.4) (1H)
8 177.8 -
–OH 8 - 13.7 (br s) (1H)
8a 101.3 -
9 186.8 -
9a 105.7 -
10a 85.1 -
11 20.7 1.94 (s) (3H)
12 171.3 -
12a 54.3 3.73 (s) (3H)
13 15.6 1.09 (d, 6.7) (3H)
14 17.3 1.01 (d, 6.4) (3H)
1′ 159.6 -
1′–OH - 11.5 (br s) (1H)
2′ 118.1 -
3′ 150.2 -
4′ 109.3 6.69 (s) (1H)
4a′ 156.7 -
5′ 68.7 4.07 (d, 1.3) (1H)
6′ 28.5 2.28 (dddq, 11.3, 6.7, 6.5, 1.3) (1H)
7′ 33.6 2.48 (dd, 19.2, 11.3) (1H)
2.35 (dd, 19.2, 6.5) (1H)
8′ 177.6 -
8′–OH - 13.7 (br s) (1H)
8a′ 102.1 -
9′ 186.6 -
9a′ 106.3 -
10a′ 84.1 -
11′ 20.6 1.96 (s) (3H)
12′ 68.7 4.14 (dd, 13.0, 7.0) (1H)
3.75 (dd, 13.0, 4.7) (1H)
12′–OH 3.28 (m) (1H)
13′ 17.7 1.04 (d, 6.7) (3H)