Position |
δC
|
δH (J in Hz) |
1 |
159.2 |
- |
–OH 1 |
- |
11.5 (br s) (1H) |
2 |
116.7 |
- |
3 |
149.6 |
- |
4 |
109.2 |
6.66 (s) (1H) |
4a |
156.8 |
|
5 |
68.8 |
4.02 (d, 9.5) (1H) |
6 |
31.3 |
2.05 (ddq, 10.3, 9.5, 6.7) (1H) |
7 |
36.7 |
2.36 (dq, 10.3, 6.4) (1H) |
8 |
177.8 |
- |
–OH 8 |
- |
13.7 (br s) (1H) |
8a |
101.3 |
- |
9 |
186.8 |
- |
9a |
105.7 |
- |
10a |
85.1 |
- |
11 |
20.7 |
1.94 (s) (3H) |
12 |
171.3 |
- |
12a |
54.3 |
3.73 (s) (3H) |
13 |
15.6 |
1.09 (d, 6.7) (3H) |
14 |
17.3 |
1.01 (d, 6.4) (3H) |
1′ |
159.6 |
- |
1′–OH |
- |
11.5 (br s) (1H) |
2′ |
118.1 |
- |
3′ |
150.2 |
- |
4′ |
109.3 |
6.69 (s) (1H) |
4a′ |
156.7 |
- |
5′ |
68.7 |
4.07 (d, 1.3) (1H) |
6′ |
28.5 |
2.28 (dddq, 11.3, 6.7, 6.5, 1.3) (1H) |
7′ |
33.6 |
2.48 (dd, 19.2, 11.3) (1H) |
|
|
2.35 (dd, 19.2, 6.5) (1H) |
8′ |
177.6 |
- |
8′–OH |
- |
13.7 (br s) (1H) |
8a′ |
102.1 |
- |
9′ |
186.6 |
- |
9a′ |
106.3 |
- |
10a′ |
84.1 |
- |
11′ |
20.6 |
1.96 (s) (3H) |
12′ |
68.7 |
4.14 (dd, 13.0, 7.0) (1H) |
|
|
3.75 (dd, 13.0, 4.7) (1H) |
12′–OH |
|
3.28 (m) (1H) |
13′ |
17.7 |
1.04 (d, 6.7) (3H) |