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. 2016 Jan 20;21(1):117. doi: 10.3390/molecules21010117

Table 4.

RCM of dienes 1, 9 and 11 with catalysts 10a and 10b.

Diene Substrate RCM Product Catalyst a (mol %) t (min) Yield (%) Catalyst b (mol %) t (min) Yield (%) b
1 2 10a-synGII (1.0) 30 >98 10a-synHGII (1.0) 5 >99
1 2 10b-synGII (1.0) 60 70 10b-synHGII (1.0) 12 >99
9 10 10a-synGII (1.0) 35 >95 10a-synHGII (1.0) 6 >99
9 10 10b-synGII (1.0) 60 66 10b-synHGII (1.0) 60 95
11 12 10a-synGII (5.0) 30 92 10a-synHGII (5.0) 30 >99
11 12 10b-synGII (5.0) 60 44 10b-synHGII (5.0) 120 94

a ref. [47]: reactions conducted in CD2Cl2 (0.1 M) at 30 °C; b ref. [47]: reactions conducted in C6D6 (0.1 M) at 60 °C.