Table 2.

Identified compounds in extract of HGKYC and in rat serum after oral administration of HGKYC in positive and negative ion mode.

No.	TR (min)	Formula	[M + H]+ (Error, ppm)	[M − H]− (Error, ppm)	Fragment Ions in		Identified Compounds		Ref.
					Positive (+) Ion Mode	Negative (−) Ion Mode	In Extract	In Serum
1	0.77	C6H14N4O2		173.1046 (1.2)		131.0829	Arginine s	−	[10]
2	0.78	C5H13NO	104.1070 (0.7)		60.0832 [M + H − H − C2H5O]+		Choline s	+	[10]
					58.0680
3	0.85	C5H9NO2	116.0705 (−0.7)		70.0671 [M + H − HCOOH]+		Proline	−	[11]
4	0.9	C5H11NO2	118.0861 (−0.7)	116.0721 (3.5)	72.0818 [M + H − HCOOH]+		Betaine s	+	[10]
					58.0676, 55.0566
5	1.07	C5H5N5	136.0717 (−0.2)		119.0353 [M + H − H − NH3]+		Adenine s	−	[10]
					92.0251 [M + H − H − NH3 − HCNN]+
6	1.08	C6H5NO2	124.0392 (−0.5)		106.0278 [M + H − H2O]+		Nicotinic acid s	−
					79.0425, 78.0348
7	1.08	C5H7NO3	130.0499 (−0.6)		84.0461 [M + H − HCOOH]+		l-Pyroglutamic acid s	+	[10]
					56.0530 [M + H − H − NH3 − HCNOOH]+			+
8	1.13	C9H11NO3	182.0806 (−3.3)		165.0547 [M + H − H − NH3]+		Tyrosine s	+	[10]
					136.0761 [M + H − HCOOH]+
					119.0487 [M + H − HCOOH − H2O]+
					91.0548
9	1.17	C6H13NO2	132.1018 (−1.1)		86.0964 [M + H − HCOOH]+,		Isoleucine s	+	[10]
					69.0711 [M + H − HCOOH − NH3]+
10	1.21	C9H8O3	165.0546 (0.02)		123.0448 [M + H − H − C2H2O]+		p-Coumaric acid s	+	[10]
					95.0500 [M + H − H − C2H2O − CO]+
					77.0397 [M + H − H − C2H2O − CO − H2O]+
					65.0414
11	1.73	C7H6O5	171.0285 (−1.7)	169.0143 (0.4)	153.0180 [M + H − H2O]+	125.0253 [M − H − CO2]−	Gallic acid s	−	[10]
					107.0131 [M + H − H2O − HCOOH]+	79.0217 [M − H − CO2 − HCOOH]−
12	2.04	C9H11NO2		164.0716 (−0.9)		147.0438 [M − H − NH3]−	Phenylalanine s	+	[10]
						103.0560 [M − H − NH3 − CO2]−
13	2.54	C8H8O4		167.0350 (0.2)		123.0449 [M − H − CO2]−	Vanillic acid	−	[12]
						93.0358 [M − H − CO2 − OCH3]−
						97.0283, 69.0341, 65.0399
14	2.92	C7H6O4		153.01989 (3.6)		109.0309 [M − H − CO2]−	Protocatechuic acid	−	[13]
						91.0208 [M − H − CO2 − H2O]−
15	3	C5H7NOS	130.0316 (−3.9)	128.0442 (1.0)	103.0536 [M + H − HCN]+		Epigoitrin s	−	[14]
					84.0819 [M + H − HCOOH]+
					70.0657, 60.9750
16	3.08	C11H12N2O2		203.0825 (−0.4)		142.0664 [M − H − NH3 − CO2]−	Tryptophan s	+	[10]
						116.0513 [M − H − NH3 − 2OCH2]−
17	3.83	C7H6O3		137.0248(2.8)		119.0145 [M − H− H2O]−	Protocatechuic aldehyde s	−	[13]
						108.0288 [M − H − CO]−
						92.0284
18	3.87	C14H20O7		299.1140 (1.3)		137.0244 [M − H − Glc]−	Salidroside s	−	[15]
						119.0335 [M − H − Glc − H2O]−
						93.0357, 59.0172
19	4.31	C8H8O5		183.0300 (0.7)		168.0065 [M − H − CH3]−	Methyl gallate s	+	[13]
						124.0175, 78.0136
20	4.49	C15H18O9		341.0881 (0.8)		179.0352 [M − H − Glc]−	Caffeoylglucose	+	[13]
						135.0454 [M − H − Glc − CO2]−
21	4.49	C15H14O6	291.0860 (−0.9)		207.0643, 147.0439		Catechin s		[13]
					139.0392, 123.0440
22	4.55	C16H18O9	355.1023 (−0.1)	353.0878 (3.0)	163.0386 [M + H − H − Glc − OCH2]+	191.0564 [M − H − Glc]−	Chlorogenic acid s	−	[16]
					145.0280, 117.0329
23	4.77	C17H24O9	373.1487 (−1.6)				Syringoside s	−	[17]
24	4.96	C9H8O4		179.035 4 (2.3)		135.0459 [M − H − CO2]−	Caffeic acid s	+	[13]
25	5.15	C11H10O5	223.0595 (−2.5)	221.0456 (0)	162.0302 [M + H − H − CH3 − HCOOH]+	206.0213 [M − H − CH3]−	Isofraxidin s	−	[16]
						190.9989 [M − H − OCH3]−
						177.0184 [M − H − CO2]−
						163.0003 [M − H − OCH2 − CO]−
26	5.36	C20H23O4N	342.1695 (−1.3)	340.1557 (0.8)	297.1110 [M + H − HCN − H2O]+	310.1088 [M − H − OCH2]−	Magnoline	−	[14]
					282.0881 [M + H − HCN − H2O − CH3]+	252.0404 [M − H − CO2 − NH3 − HCNN]−
					237.0902, 191.0848, 58.0680	224.0509 [M − H − CO2 − NH3 − HCNN − H2O]−
						162.0180, 118.0288,79.9591
27	5.51	C19H18O11	423.0925 (0.7)	421.0780 (0.8)	405.0776 [M + H − H2O]+	331.0459 [M − H − HCOOH − CO2]−	Mangiferin	−	[18]
					339.0520, 327.0493, 303.0478	271.0253 [M − H − Xyl]−
					285.0417	259.0230 [M − H − Glc]−
					273.0395,
28	5.54	C17H20N4O6	377.1450 (−1.6)		359.1339, 243.0878, 198.0644		Riboflavin	−	[19]
29	5.97	C17H20O9		367.1038 (0.9)		191.0561	3-Feruloyquinic acid	−	[13]
30	6.07	C23H28O11		479.1569 (2)		449.1433, 327.1081	Paeoniflorin s	−	[20]
						255.0647, 165.0568, 121.0297
31	6.08	C9H10O5		197.0458 (1.4)		169.0147, 124.0175, 78.0178	Syringic acid s	+
32	6.2	C9H8O3		163.0400 (−0.4)		119.0505 [M − H − CO2]−	trans-p-Coumaric acid s	+
						93.0352 [M − H − CO − C2H2O]−
33	6.48	C34H46O18	743.2744 (−1.8)	741.2628 (2.2)		579.2111 [M − H − Glc]−	Eleutheroside E s	−	[13]
						417.1579 [M − H − 2Glc]−
34	6.48	C28H36O13		579.2100 (2.9)			Eleutheroside E1	−	[13]
35	6.82	C10H10O4		193.0508 (0.8)		178.0263 [M − H − CH3]−	Ferulic acid s	−	[13]
						134.0375 [M − H − CH3 − CO2]−
36	6.9	C20H22O8	391.1372 (−3.9)	389.1252 (2.7)	229.0859 [M + H − H − Glc]+	227.0718 [M − H − Glc]−	Polydatin s	+	[21]
						185.0612 [M − H − Glc − C2H2O]−
37	6.91	C14H12O3	229.0850 (3.9)	227.0715 (0.7)	183.0788	185.0601, 143.0508	Resveratrol s	+	[22]
					165.0690 [M + H − H2O − HCOOH]+
					107.0489, 91.0540
38	6.95	C26H28O13		547.1479 (4)			6-C-Arabinosyl-8-C-Glucosyl-Chrysin	+	[23]
						487.1279
						457.1169 [M − H − C3H6O − OCH2]−
						427.1052
						409.0946, 367.0839
						337.0734 [M − H − Glc − OCH2]−
39	7.04	C27H30O16	611.1584 (−3.6)	609.1482 (3.8)	465.1016 [M + H − H − Rha]+	301.0354 [M − H − Rha − Glc]−	Rutin s	−	[18]
					303.0501 [M + H − H − Rha − Glc]+	271.0228
40	7.10	C21H18O12		461.0736 (2.2)		285.0416 [M − H − Glc acid]−	Scutellarin s	+	[18]
41	7.19	C21H20O12		463.0891 (1.9)		301.0360 [M − H − Glc]−	Hyperoside s	+	[24]
						271.0250 [M − H − Glc − OCH2]−
						255.0310 [M − H − O − Glc − OCH2]−
						178.9998, 151.0041
42	7.21	C23H24O13	509.1271 (−3.6)	507.1156 (2.3)	347.0750 [M + H − H − Glc]+,	345.0632 [M − H − Glc]−	Viscidulin III-	−	[25]
					332.0523 [M + H − H − Glc − CH3]+	330.0383 [M − H − Glc − CH3]−	Glucopyranoside
					314.0409	315.0174 [M − H − Glc − 2CH3]−
43	7.32	C26H28O13		547.1479 (4.0)		487.1279	6-C-Glucosyl-8-C-Arabinosyl-Chrysin		[23]
						457.1169 [M − H − C3H6O − OCH2]−
						427.1052
						409.0946, 367.0839
						337.0734 [M − H − Glc − OCH2]−
44	7.41	C21H20O13		479.0831 (0.1)		441.0761, 435.0957	Isomyricitrin	−	[26]
						313.0570, 165.0548
45	7.59	C25H24O12	517.1326 (−2.8)	515.1199 (0.7)	499.1177 [M + H − H2O]+	353.0889	Cynarin	−	[13]
					163.0382	191.0562
						179.0347
46	7.63	C33H40O18		723.2144 (0.2)			Ligustroflavone s	−	[27]
47	7.63	C31H42O17	687.24992 (0.6)	685.2372 (3.4)		523.1831 [M − H − Glc]−	Specnuezhenide	−	[15]
						454.1404, 421.1508
						299.1137, 223.0603
48	7.74	C20H18O11	435.0913 (−2)	433.0784 (1.7)	303.0493 [M + H − H−Arab]+	301.0294 [M − H − Arab]−	Quercetin-3-arabinoside	−	[23]
						271.0257 [M − H − Arab − OCH2]−
						255.0314, 178.9989, 151.0036
49	7.93	C21H20O9	417.1169 (−2.6)	415.1044 (2.2)	399.1071 [M + H − H2O]+	325.0692 [M − H − C3H6O3]−	Chrysin-8-C-glucoside	+	[23]
					297.0758 [M + H − H − C4H8O4]+	295.0624 [M − H − C4H8O4]−
					279.0639 [M + H − H − C4H8O4−H2O]+	267.0676 [M − H − C4H8O4 − CO]−
					267.0644 [M + H − H − C4H8O4 − 2H2O]+	149.0237
50	7.97	C21H20O11	449.1063 (−3.3)	447.0947 (3.1)	303.0488 [M + H − H − Rha]+	301.0379 [M − H − Rha]−	Quercetrin s	−	[18]
					287.0549 [M + H − H − O − Rha]+	271.0265 [M − H − Rha − OCH2]−
					129.0543, 85.0289	255.0315, 178.9983
					85.0286	151.0041
51	8.22	C32H38O16	679.2215 (−2.6)		533.1669 [M + H − H − Rha]+		hexandraside E	−	[14]
					371.1096 [M + H − H − Rha − Glc]+
					315.0457 [M + H − H − Rha − Glc − C4H8]+
52	8.52	C38H48O20	825.2794 (−2.1)		663.2238 [M + H − H − Glc]+		Diphylloside B	−	[14]
					517.1674 [M + H − H − Rha − Glc]+
					355.1199 [M + H − H − Rha−2Glc]+
					299.0562 [M + H − H − Rha−2Glc − C4H8]+
53	8.53	C26H28O11	517.1693 (−2.2)		355.1169 [M + H − H − Glc]+		Icarrin C	−	[14]
					299.0524 [M + H − H—Glc − C4H8]+
54	8.58	C21H18O11	447.0912 (−2.2)	445.07858 (2.1)	271.0595 [M + H − H − O − Glc]+	269.0459 [M − H − O − Glc]−	Baicalin s	+	[23]
55	8.82	C38H48O19	809.28357 (−3.3)	807.2011 (0.33)	663.2266 [M + H − H − Xyl]+		Epimedin B	−	[14]
					517.1687 [M + H − H − Xyl − Rha]+
					355.1182 [M + H − H − Xyl − Rha − Glc]+
					299.0542 [M + H − H − Xyl − Rha − Glc − C4H8]+
56	8.86	C22H22O9	431.1318 (−4.2)	429.1101 (0.3)	269.0802 [M + H − H − Glc]+		Ononin	−
57	8.87	C21H22O9		417.1191 (0)		255.0678 [M − H − Glc]−	Polygonimitin B		[18]
						211.0773 [M − H − Glc − CO2]−
58	8.89	C21H20O11	449.1063 (−3.3)	447.0946 (3.1)	303.0488 [M + H − H − Rha]+	301.0379 [M − H − Rha]−	Isoquercetrin	−
					287.0549 [M + H − H − O − Rha]+	271.0265 [M − H − Rha − CH2]−
					129.0543,85.0289	255.0315,178.9983
59	8.9	C32H38O15	663.2265 (−2.7)	661.2169 (4.7)	517.1667 [M + H − H − Rha]+	515.1907	Epimedoside A	−
					355.1180 [M + H − H − Rha − Glc]+	353.1050
					299.0559 [M + H − H − Rha − Glc − C4H8]+
60	9.0	C17H14O8	347.0751 (−3.1)		332.0523, 317.0288, 314.0414		Viscidulin III	−	[23]
					289.0340, 169.0125
61	9.04	C39H50O20	839.2967 (−0.2)		677.2346 [M + H − H − Glc]+		Epimedin A	−
					531.1881 [M + H − H − Glc − Rha]+
					369.1342 [M + H − H − 2Glc − Rha]+
					313.0691 [M + H − H − 2Glc − Rha − C4H8]+
62	9.15	C33H40O16	693.2365 (−3.4)		547.1791 [M + H − H − Rha]+		anhydroicaritin	−	[14]
					531.1895 [M + H − H − Glc]+		-3,7-di-O-glucoside
					385.1284 [M + H − H− Rha − Glc]+
					369.1321 [M + H − H − O − Rha − Glc]+
					313.0687 [M + H − H − O − Rha − Glc − C4H8]+
63	9.15	C30H32O13		599.1787 (2.8)		581.1699 [M − H − H2O]−	Benzoyloxypaeoniflorin	−	[20]
						477.1593 [M − H − C7H6O2]−
						449.7983 [M − H − C7H6O2 − CO]−
						431.1372 [M − H − H2O − Xyl]−
						281.0676 [M − H − H2O − Xyl − C5H10O5]−
64	9.45	C22H22O10	447.1269 (−3.8)	445.1143 (0.6)	285.0757 [M + H − H − Glc]+,	430.0906 [M − H − CH3]−	Wogonin-7-O-glucoside	−	[23]
					270.0526 [M + H − H − Glc − CH3]+	268.0456 [M − H − CH3 − Glc]−
65	9.51	C22H20O12	477.1026 (−2.3)	475.0892 (2)	301.0706 [M + H − H − Glucuronic acid]+	299.0573 [M − H − Glucuronic acid]−	5,4′-Dihydroxy-8-methoxy-flavone-7-O-glucuronide	+	[23]
					286.0470 [M + H − H − Glucuronic acid − CH3]+	284.0324 [M − H − Glucuronic acid − CH3]−
66	9.8	C15H10O7		301.0356 (0.9)		273.0396 [M − H − CO]−	Quercetin	−	[18]
						245.0407 [M − H − CO − H2O]−
						178.9978
						151.0035, 121.0292
						107.0144
67	9.9	C21H18O11	447.0919 (−0.7)		271.0595		Baicalein-6-O-glucuronide	+	[23]
68	9.96	C11H12O4		207.0667 (2.1)		179.0345, 135.0469	Ethyl Caffeate s		[23]
69	9.99	C22H22O11	461.1088 (−0.4)	459.0949 (3.4)	285.0759, 270.0522	283.0624, 268.0387, 175.0256, 113.0261	Wogonoside s	−	[23]
70	10.03	C22H20O11	461.1069 (−2)	459.0949 (3.4)	285.0759 [M + H − H − Glucuronic acid]+	283.0624 [M − H − Glucuronic acid]−	Oroxyloside s	+	[23]
					270.0522 [M + H − H − Glucuronic acid − CH3]+	268.0387 [M − H − Glucuronic acid − CH3]−
71	10.33	C39H50O19	823.30066 (−1.5)		677.2421 [M + H − H − Rha]+		Epmedin C	−	[14]
					531.1840 [M + H − H−2Rha]+
					369.1326 [M + H − H−2Rha − Glc]+
					313.0708 [M + H − H−2Rha − Glc − C4H8]+
72	10.34	C27H30O11	531.1846 (−2.8)		369.1326 [M + H − H − Glc]+		Icariside I s	−	[14]
					313.0695 [M + H − H − Glc − C4H8]+
73	10.55	C33H40O15	677.24256 (−2.1)	675.2326 (4.7)	531.1847 [M + H − H − Rha]+	367.1099	Icariin s	+	[14]
					369.1332 [M + H − H − Rha − Glc]+	269.0461 [M − H − Rha − Glc]−
					313.0712 [M + H − H − Rha − Glc − C4H8]+
74	11.3	C9H10O3		165.0557 (0)		150.0333 [M − H − CH3]−	Paeonol s	+	[28]
						135.0094 [M − H − OCH2]−
					122.0385, 91.0208
75	11.44	C15H10O6		285.0407 (0.8)		241.0517 [M − H − CO2]−	Kaempferol s	+	[18]
						211.0408 [M − H − CO2−OCH2]−
						195.0463,167.0509
76	11.56	C16H12O6		299.0563 (0.7)		284.0327 [M − H − CH3]−	5,7,4’-Trihydroxy-8-	−	[23]
						240.0424 [M − H − CH3 − CO2]−	methoxyflavone
						171.0452,153.9909
						125.9968
77	11.59	C16H12O7		315.0510 (0)		300.0279 [M − H − CH3]−	Isorhamnetin s	+	[29]
						282.0178 [M − H − CH3 − H2O]−
						255.0240, 151.0016
78	11.71	C32H38O15	663.3011 (3.1)	661.2163 (−3.5)	517.1667 [M + H − HCOOH]+	353.0978 [M − H − Rha − Glc]−	Ikarisoside B	+	[26]
					355.1165 [M + H − H − Rha − Glc]+
					299.0599 [M + H − H − Rha − Glc − C4H8]+
79	11.73	C15H10O5	271.0597 (−1.6)	269.0456(1.9)	253.0500 [M + H − H2O]+	251.036 [M − H − H2O]−	Baicalein s	+	[23]
					123.0080	223.0407, 169.0664
80	12.15	C31H36O14		631.2050 (2.8)		481.1616 [M − H − Xyl]−	Ikarisoside F	+	[26]
						353.1076, 352.0928, 341.0528
81	12.37	C16H12O4	269.0805 (−1.2)	267.0664 (0.4)	254.0576, 237.0532	252.0430, 223.0396, 195.0445	Formononetin s	−	[10]
					197.0599	132.0221
					181.0644, 118.0416
82	12.65	C26H28O10	501.1744 (−2.3)	499.1618 (1.6)	355.1169 [M + H − H − Rha]+	353.1043 [M − H − Rha]−	Baohuoside II s	+	[14]
					299.0559 [M + H − H − Rha − C4H8]+	309.0445 [M − H − Rha − CO2]−
					147.0645,129.0533
83	13.34	C33H40O15	677.2417 (−3.4)	675.2326 (4.7)	531.1847 [M + H − H − Rha]+	367.1099 [M − H − Rha − Glc]−	Baohuoside VII	+	[26]
					369.1324 [M + H − H − Rha − Glc]+	352.0997
					313.0712 [M + H − H − Rha − Glc − C4H8]+
84	13.49	C43H70O15	827.4768 (−2.3)		455.3660, 437.335		Astragaloside II	−	[10]
					175.0610,157.0474,143.1087
85	13.74	C42H68O13	781.4736 (0.4)		745.4447		Saikosaponin a	−	[30]
					619.4203, 583.3921
					455.3486, 437.3374
					419.3231
86	13.79	C16H12O5	285.0754 (−1.3)	283.0615 (0.9)	270.0514 [M + H − H − CH3]+	268.0380 [M − H − CH3]−	Wogonin s	+	[23]
					179.0488	163.0036
87	13.80	C32H38O14	647.2323 (−1.7)		501.1726 [M + H − H − Rha]+		Sagittatoside B	+	[26]
					465.1557 [M + H − H − Rha − HCOOH]+
					409.0917, 355.1171
					299.0594
88	13.81	C16H12O5	285.0754 (−1.3)	283.0615 (0.9)	270.0514 [M + H − H − CH3]+	268.0380 [M − H − CH3]−	Oroxylin A s	+	[23]
					179.0488	163.0036
89	13.82	C32H38O14	647.2323 (−1.7)		629.2323, 501.1726,		2′′-O–Rhamnosyl-ikarisoside A		[26]
					465.1557, 355.1171, 299.0059
90	13.9	C33H40O14	661.2470 (−3.1)	659.2374 (4.4)	515.1897 [M + H − H − C6H10O4]+	366.1127	2′′-O-Rhamnosyl-ikariside II	+	[14]
					369.1333, 355.0809, 313.0703
91	13.96	C15H10O4	255.0642 (−3.9)	253.0708 (0.7)	153.0177 [M + H − H − C5H8O − H2O]+	209.0609 [M − H − CO2]−	Chrysin s	+	[23]
					103.0544	143.0505, 63.0276
92	14.01	C17H14O6	315.0856 (−2.3)	313.0718 (0.2)	300.0618, 285.0396	298.0485, 283.0252, 211.0396	Kumatakenin		[29]
					257.0440, 182.9919, 154.9964	155.0506
93	14.5	C24H32O7	433.2215 (−1.3)		415.2106 [M + H − H2O]+		Schisandrin s	+	[31]
					400.1869 [M + H − H2O − CH3]+
					384.1923 [M + H − H − OCH3 − H2O]+
					359.14907 [M + H − H2O − C4H8]+
					315.1223
94	14.63	C27H30O10	515.1901 (−2)	513.1780 (2.7)	369.1321 [M + H − H − Rha]+	367.1134 [M − H − Rha]−	Icarisid II s	+	[14]
					313.0700 [M + H − H − Rha − C4H8]+	351.0882 [M − H − O − Rha]−, 323.0912
95	15.2	C45H72O16	869.4881 (−1.4)		689.4234, 437.3396		Astragaloside I s	−	[10]
					217.0720, 157.0506, 143.1059
96	15.5	C23H28O7	417.1890 (−4.2)		399.1815 [M + H − H2O]+		Schisandrol B	−	[31]
					384.1501 [M + H − H2O − CH3]+
					368.1618 [M + H − H2O−OCH3]+
					357.1394 [M + H − H2O − C3H6]+
					343.1187 [M + H − H2O − C4H8]+
97	16.02	C30H48O5	489.3566 (−1.8)	487.3434 (1)	453.3324 [M + H − H − 2H2O]+	469.3361 [M − H − H2O]−	Tormentic acid	+	[15]
					407.3254 [M + H − HCOOH−2H2O]+	407.1533
					201.1702, 127.0767
98	16.07	C21H20O6	369.1323 (−2.6)		313.0693		Icaritin	−	[14]
99	16.08	C15H10O5	271.0596 (−2)	269.0460 (1.5)		225.0560, 241.0514, 197.0608, 182.0375	Emodin s	+	[18]
100	17.88	C23H30O6	403.2112 (−0.8)		388.1848 [M + H − H − CH3]+,		Schisanhenol	−	[31]
					372.1919 [M + H − H − OCH3]+
					371.1859 [M + H − H − CH3OH]+
					333.1326, 302.1149
101	19.09	C28H34O9	515.2264 (−2.3)		415.2009 [M + H − H − C4H6COOH]+		Schisantherin B	−	[31]
					385.1637 [M + H − H − C4H6COOH − OCH2]+
					355.1534, 343.1160, 316.0939
102	20.31	C24H32O6	417.2259 (−3)		402.1999 [M + H − H − CH3]+		Schizandrin A s	−	[31]
					386.2059 [M + H − H − OCH3]+
					347.1480 [M + H − H − C5H10]+
					316.1289 [M + H − H − C5H10 − OCH3]+
					301.1058, 285.1104, 273.1091, 242.0911
103	21.3	C23H28O6	401.1948 (−2.6)		386.1728 [M + H − H − CH3]+		γ-Schizandrin B s	−	[31]
					331.1168 [M + H − H − C5H10]+
					300.0987, 242.0929
104	21.87	C22H24O6	385.1638 (−1.9)		355.1561 [M + H − H − OCH2]+		Schizandrin C	−	[31]
					315.0895 [M + H − H − C5H10]+
					285.0757 [M + H − H − C5H10−OCH2]+
					257.0809, 242.0588, 227.0703, 153.0663
105	22.98	C32H50O5	515.3723 (−1.6)	513.3594 (1.7)	409.3466, 191.1793	495.3496 [M − H − H2O]−	19α−Hydroxyl−3−acetyl ursolic acid	−	[15]
						469.3720 [M − H − CO2]−
106	23.56	C30H48O3		455.3537 (1.3)			Oleanic acid s	−	[15]
107	23.73	C30H48O3		455.3537 (1.3)			Ursolic acid	−	[15]

^“s” Identified with reference compounds; “+”: detected and “−”not detected.