Table 1.

Parameters of the catalytic cross-linking of PDMS and EHDMS.

Catalyst	сcatalyst, mol/L	τpot-life at RT, min	τcuring at RT	τcuring, min at 80 °С	DSC Data			−ΔH, J/g
					Tonset, °С	Tpeak, °С	Tendset, °С
cis-1	1.0 × 10−3	120	24 h	20	87.2	105.8	121.6	8.6
cis-2	1.0 × 10−3	150	24 h	10	82.2	101.8	118.0	10.1
cis-3	1.0 × 10−3	120	20 h	10	84.6	92.1	118.0	15.5
cis-4	1.0 × 10−3	20	3 h	5	not measured
	1.0 × 10−4	60	6 h	30	84.7	90.6	94.2	17.2
	5.0 × 10−5	260	36 h	60	83.8	106.6	111.5	17.2
	1.0 × 10−5	−	30 day	600	115.2	145.4	153.3	24.1
trans-1	1.0 × 10−3	−	30 day	120	133.0	141.6	145.0	10.4
trans-2	1.0 × 10−3	−	14 day	80	126.9	130.3	133.4	10.7
trans-3	1.0 × 10−3	−	5 day	60	110.2	115.3	120.2	10.1
trans-4	1.0 × 10−3	240	24 h	15	98.6	108.8	115.6	7.6
	1.0 × 10−5	−	20 day	80	107.6	133.0	157.5	19.0
Karstedt’s catalyst	1.0 × 10−4	0.7	0.1 h	−	not measured
	5.0 × 10−5	1.1	0.2 h	−	not measured
	1.0 × 10−5	3	6 h	−	35.4	51.3	65.9	4.5