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. 2016 Jul 9;21(7):900. doi: 10.3390/molecules21070900

Table 1.

Recent visible light active photocatalysts for water splitting.

Photocatalysts Band Gap (eV) Illumination Hydrogen Production Ref.
Pt, Cr, Ta Doped TiO2 N/A Visible light (>420 nm) 11.7 μmol·h−1·g−1 [71]
Cu-Ga-In-S/TiO2 N/A 300 W Xe arc lamp (385–740 nm) 50.6 μmol·h−1 [72]
1 wt.%Pt/C-HS-TiO2 2.94 Visible light 5713.6 μmol·h−1·g−1 [73]
Platinized sub-10 nm rutile TiO2 (1 wt.% Pt) 2.7–2.9 Xe lamp (PLS-SXE, 300–2500 nm) with (UVREF: 320–400 nm, ca. 83 mW·cm−2; UVCUT400: 400–780 nm, ca. 80 mW·cm−2) 932 μmol·h−1·g−1
visible light
1954 μmol·h−1·g−1
simulated solar light
[74]
Rh- and La-codoped SrTiO3 N/A 300 W Xe lamp fitted with a cutoff filter (λ > 420 nm) 84 μmol·h−1 [75]
Cu1.94S-ZnxCd1−xS (0 ≤ x ≤ 1) 2.57−3.88 visible-light irradiation (λ > 420 nm) 7735 μmol·h−1·g−1 [76]
MoS2/Co2O3/poly(heptazine imide) N/A visible light irradiation 0.67 μmol·h−1 [77]
Bi4NbO8Cl 2.4 visible light 6.25 μmol·h−1 [78]
CdS nanorod/ ZnS nanoparticle N/A visible light irradiation (>420 nm) 239,000 μmol·h−1·g−1 [79]
Ni/CdS/g-C3N4 N/A 300 W Xe lamp (≥420 nm) 1258.7 μmol·h−1·g−1 [80]
CdS/WS/graphene N/A visible light irradiation (>420 nm) 1842 μmol·h−1·g−1 [81]
V-doped TiO2/RGO N/A visible light irradiation 160 μmol·h−1 [82]
Pt/g-C3N4 Conjugated Polymers 2.56 visible light irradiation (>420 nm) 1.2 μmol·h−1 [83]
Au–TiO2 Nanohybrids N/A Vis-NIR irradiation (>420 nm ) 647,000 μmol·h−1·g−1 [84]
SrTiO3:La,Rh/Au/BiVO4:Mo N/A 300 W Xe lamp fitted with a cutoff filter (λ > 420 nm) 90 μmol·h−1 [85]
CoOx-B/TiO2-TaON N/A 150 W Xe Lamp arc (>400 nm) 40 μmol·h−1 [86]
MoS2/CuInS2 N/A 300 W Xe lamp fitted with a cutoff filter (λ > 420 nm) 202 μmol·h−1·g−1 [87]
Copper-Organic Framework; H2PtCl6 2.1 UV-Visible irradiation 30 μmol·h−1·g−1 [88]