Table 1.
Analyte No. | Compound | UV λmax [nm] | [M − H]− m/z | Fragmentary Ions |
---|---|---|---|---|
1 | Apigenin 7-O-β-d-(6′′-trans-p-coumaroyl)-glucoside | 269, 317 | 577 | 307, 269 |
2 | Kaempferol 3-O-glucoside (astragalin) | 235sh, 265, 342 | 447 | 327, 285, 255 |
3 | Quercetin 3-O-[(4′′′-O-E-feruloyl)-α-rhamnopyranosyl-(1→6)]-β-glucopyranoside | 251, 333 | 785 | 623, 609, 591, 477, 301, 271 |
4 | Verbascoside | 245, 329 | 623 | 461, 315 |
5 | Lamalbid (lamiridoside) | 241 | 467 * | 421, 259 |
6 | Shanzhiside methyl ester | 221 | 451 * | 405, 283, 225, 179, 143 |
7 | Phlinoside D | 216, 328 | 769 | 637, 607, 593, 461 |
8 | Quercetin 3-O-α-rhamnopyranosyl-(1→2)[(4′′′′-O-E-feruloyl)-α-rhamnopyranosyl-(1→6)]-β-glucopyranoside | 251, 332 | 931 | 887, 785, 769, 755, 738, 702, 609, 562, 490, 301 |
* [M + HCOOH − H]−.