. 2018 Oct 31;23(11):2829. doi: 10.3390/molecules23112829

Table 3.

Mass data of glucosinolates identified in the crude MeOH extract of M. arvensis *.

Compound	[M + Na]⁺ m/z	MS/MS (%)
3-Hydroxypropyl-GLS	320	219 (2) [(M + Na)-RCNOH]⁺; 100 (100) [CH₂CHCH₂NCS + H]⁺; 72 (10) [CH₂NCS]⁺
3-Hydroxybutyl-GLS	334	219 (35) [(M + Na)-RCNOH]⁺; 100 (100) [CH₂CHCH₂NCS + H]⁺
Gluconapin (3-Butenyl-GLS)	316	185 (3) [(M + Na)-RCNOH-H₂S]⁺; 154 (2) [(M + Na)-Glu]⁺; 72 (10) [CH₂NCS]⁺; 58 (19) [NCS]⁺
Isobutyl-GLS	318	186 (2) [(M + Na)-RCNOH-H₂S]⁺; 100 (100) [CH₂CHCH₂NCS + H]⁺; 72 (10) [CH₂NCS]⁺
Glucoviorylin (2-(Methylthio)-ethyl-GLS)	336	220 (38) [(M + Na)-RCNOH]⁺; 174 (2) [(M + Na)-Glu]⁺; 100 (100) [CH₂CHCH₂NCS + H]⁺; 72 (10) [CH₂NCS]⁺
Glucoiberverin (3-(Methylthio)-propyl-GLS)	350	219 (15) [(M + Na)-RCNOH]⁺; 100 (100) [CH₂CHCH₂NCS + H]⁺; 58 (13) [NCS]⁺
Glucotropaeolin (Benzyl-GLS)	352	220 (2) [(M + Na)-RCNOH]⁺; 100 (100) [CH₂CHCH₂NCS + H]⁺; 72 (10) [CH₂NCS]⁺

* Glucosinolates have been analyzed as desulphoglucosinolates.