Table 2.

Solution calorimetric data of US2 samples

Sample	Trial	Weight (g)	Heat of solution (∆H) in J g−1 obtained experimentally						Theoretical heat of solution (∆H)
			Pre-break calibration	Post-break calibration	Mean	Overall mean	SD	RSD
BMA	1	0.10026	36.005	35.998	36.00	36.6	0.5	1.4	N/A
	2	0.10034	36.947	36.974	36.96
	3	0.10036	36.888	36.839	36.86
US2	1	0.10062	− 45.948	− 45.874	− 45.91	− 46.5	0.5	− 1.1
	2	0.10064	− 46.869	− 46.847	− 46.86
	3	0.10053	− 46.670	− 46.656	− 46.66
US2 1 (PM)	1	0.10013	− 5.951	− 5.936	− 5.94	− 5.4	0.5	− 9.0	− 4.9
	2	0.10186	− 4.974	− 4.969	− 4.97
	3	0.10071	− 5.369	− 5.356	− 5.36
US2 4	1	0.10072	− 10.823	− 10.809	− 10.82	− 10.9	0.3	− 2.8	− 29.9
	2	0.10070	− 10.726	− 10.702	− 10.71
	3	0.10050	− 11.293	− 11.277	− 11.29
US2 2.5	1	0.10008	− 15.983	− 15.968	− 15.98	− 16.3	0.6	− 3.9	− 21.6
	2	0.10035	− 17.014	− 16.986	− 17.00
	3	0.10009	− 15.866	− 15.850	− 15.86
US2 1	1	0.10045	− 14.052	− 14.003	− 14.03	− 14.4	0.4	− 3.1	− 13.2
	2	0.10045	− 14.911	− 14.894	− 14.90
	3	0.10092	− 14.292	− 14.276	− 14.28