| Crystal data |
| Chemical formula |
(C18H26N2)3[Pb4I14(C2H6OS)2]·2C2H6OS |
|
M
r
|
1864.54 |
| Crystal system, space group |
Triclinic, P
|
| Temperature (K) |
296 |
|
a, b, c (Å) |
11.5011 (10), 14.2262 (13), 16.2969 (14) |
| α, β, γ (°) |
80.305 (1), 78.449 (1), 81.753 (1) |
|
V (Å3) |
2558.5 (4) |
|
Z
|
2 |
| Radiation type |
Mo Kα |
| μ (mm−1) |
10.90 |
| Crystal size (mm) |
0.55 × 0.50 × 0.09 |
| |
| Data collection |
| Diffractometer |
Bruker APEX3 CCD area-detector |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2017 ▸) |
|
T
min, T
max
|
0.065, 0.440 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
24466, 8975, 8219 |
|
R
int
|
0.040 |
| (sin θ/λ)max (Å−1) |
0.595 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.034, 0.099, 1.07 |
| No. of reflections |
8975 |
| No. of parameters |
432 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) |
2.47, −1.72 |
