Table 3. Experimental details.

Crystal data
Chemical formula	[Mn(NCS)2(C12H9NO)4]
M r	903.91
Crystal system, space group	Monoclinic, P21/c
Temperature (K)	200
a, b, c (Å)	9.1463 (6), 20.9990 (11), 11.2177 (7)
β (°)	90.493 (7)
V (Å3)	2154.4 (2)
Z	2
Radiation type	Mo Kα
μ (mm−1)	0.46
Crystal size (mm)	0.12 × 0.03 × 0.03
Data collection
Diffractometer	Stoe IPDS1
Absorption correction	Numerical (X-SHAPE and X-RED32; Stoe, 2008 ▸)
T min, T max	0.836, 0.989
No. of measured, independent and observed [I > 2σ(I)] reflections	22833, 4717, 3912
R int	0.037
(sin θ/λ)max (Å−1)	0.639
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.040, 0.109, 1.04
No. of reflections	4717
No. of parameters	287
H-atom treatment	H-atom parameters constrained
Δρmax, Δρmin (e Å−3)	0.48, −0.42

Computer programs: X-AREA (Stoe, 2008 ▸), SHELXS97 (Sheldrick, 2008 ▸), SHELXL2014/7 (Sheldrick, 2015 ▸), XP in SHELXTL (Sheldrick, 2008 ▸), DIAMOND (Brandenburg, 1999 ▸) and publCIF (Westrip, 2010 ▸).