Table 1.

Experimental aminoxyl/oxoammonium redox potentials.

Entry	Aminoxyl Derivative	Potentiala	Ref.	Entry	Aminoxyl Derivative	Potentiala	Ref.
1		Ea = 0.77 b	60	13			60
		E1/2 = 0.73 b	73
		E1/2 = 0.84 c	75			Ea = 0.95b
2		E1/2 = 1.00 b	80
3		E1/2 = 0.90b	63	14		Ea = 1.00b	60
4		Ea = 0.91b	60	15		Ea = 0.92b	60
5		Ea = 0.86b	60	16		Ea = 1.02b	60
6		Ea = 0.82b	60	17		E1/2 = 0.89c	76
7		Ea = 0.85b	60	18		E1/2=0.91b	77
8				19		E1/2=0.84b	74
		Ea = 0.88b	60
9				20		E1/2 = 0.88b	74
		Ea = 0.91b	60
10				21		E1/2 = 0.89b	74
		Ea = 0.67b	60
11				22		E1/2=1.00b	74
		Ea= 1.01b	60	23
						E1/2=1.10c	76
12
		E1/21.05b	78	24		E1/2 = 1.31c	76
25		Ea = 0.75b E1/2 = 0.68b E1/2 = 0.80c	60 73 75	39		Ea=0.61b	60
26		Ea = 0.86b	60	40		Ea = 0.74b	60
27		Ea = 0.85b	60	41		E1/2=0.97c	78
28
		Ea=1.02c	72
				42		E1/2 =0.96c	78
29
		Ea = 0.75b	60
				43
30						E1/2 =0.93c	78
		Ea = 0.68b	60
31		E1/2 =1.00 c	72
				44		E1/2 =1.23c	78
32		E1/2 =1.06b	72
33		E1/2 = 0.74b	60
		E1/2 = 0.65b	73	45		E1/2 =0.94c	78
		E1/2 = 0.79c	75
34
		E1/2 = 0.74c	75
35				46		E1/2 =1.02c	78
		E1/2 = 0.69c	75
36
		E1/2 = 1.02c	75
				47		E1/2=1.05c	78
37
		E1/2 = 1.14c	75
38				48		E1/2 = 0.99c	78
		E1/2 =1.08c	75

^aPotentials adjusted relative to NHE, as described in ref. 17–19. In ref. 60, only the anodic peak potentials (E_a), not the mid-point potentials (E_1/2), were reported.

Abbreviations: Ac = acetyl, Bn = benzyl, Py ^⊕ = N-pyridinium, nPr=n-propyl.

^bExperimental measurements performed in H₂O.

^cExperimental measurements performed in CH₃CN.