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. Author manuscript; available in PMC: 2019 May 9.
Published in final edited form as: Chem Rev. 2018 Apr 30;118(9):4834–4885. doi: 10.1021/acs.chemrev.7b00763

Table 7.

Second order rate constants of the reaction of PINO with substrates containing activated C–H bonds.44

Substrate k (M−1 s−1) Substrate k (M−1 s−1)
graphic file with name nihms-990055-t0039.jpg 1.85 graphic file with name nihms-990055-t0040.jpg 77.6
graphic file with name nihms-990055-t0041.jpg 26.2 graphic file with name nihms-990055-t0042.jpg 20.2
graphic file with name nihms-990055-t0043.jpg 43.2 graphic file with name nihms-990055-t0044.jpg 12.8
graphic file with name nihms-990055-t0045.jpg 10.9 graphic file with name nihms-990055-t0046.jpg 2.88
graphic file with name nihms-990055-t0047.jpg 156 graphic file with name nihms-990055-t0048.jpg --
graphic file with name nihms-990055-t0049.jpg 47.6 graphic file with name nihms-990055-t0050.jpg 1.50
graphic file with name nihms-990055-t0051.jpg 26.2 graphic file with name nihms-990055-t0052.jpg 96.2
graphic file with name nihms-990055-t0053.jpg 36.3 graphic file with name nihms-990055-t0054.jpg 15.3