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. Author manuscript; available in PMC: 2018 Dec 11.
Published in final edited form as: J Am Chem Soc. 2016 Oct 26;138(44):14658–14667. doi: 10.1021/jacs.6b07981

Scheme 6.

Scheme 6.

Diagrams of Concerted and HAT Transition State Geometries for C‒H Amination, Including the Features of Stepwise Transition States vs Those Leading to Barrierless Rebound