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. Author manuscript; available in PMC: 2019 Jul 20.
Published in final edited form as: J Org Chem. 2018 Jul 6;83(14):7480–7490. doi: 10.1021/acs.joc.8b00946

Figure 1.

Figure 1.

Screening data for the cofactor/proximal ligand substituted Mb(H64V,V68A) variants in the reactions with (a) 4-(dimethylsilyl)styrene 3a or (b) 4-amino-styrene 4a, and EDA. The pie charts indicate the product distribution (light blue for Si—H and N—H insertion products 3c and 4c, respectively; blue for cyclopropanation product 3b and 4b, respectively; dark blue for multiple insertion byproduct(s)). The activity (% GC yield) is represented as filling color.