Table 2.

Chemoselectivity of myoglobin and other hemoproteins in the reaction with 4-(dimethylsilyl)styrene (3a) or para-amino-styrene (4a) and EDA.^a

Entry	Catalyst	% yield (3b+3c)b	3b:3c ratio	% yield (4b+4c) b	4b:4c ratio
1	Mb	6	3:97	65	1:99
2	Mb(H64V,V68A)	13	4:96	85	0:100
3	HRP	1	11:89	96	0:100
4	Catalase	1	9:91	6	2:98
5	P450BM3	<0.5	5:95	24	1:99
6	FL#62	4	5:95	25	1:99
7	cytochrome c	10	5:95	57	1:99

^aReaction conditions: 10 mM 3a or 4a, 10 mM EDA, 10 mM Na₂S₂O₄, 20 μM catalyst in 50 mM phosphate buffer (pH 7.0).

^bBased on GC conversion using calibration curves with isolated 3b, 3c, 4b, and 4c.