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. Author manuscript; available in PMC: 2019 Jun 26.
Published in final edited form as: Chem Mater. 2018 Mar 25;30(12):3931–3942. doi: 10.1021/acs.chemmater.8b01359

Table 3.

Results of Polymerizations in Flow for Reversible Trapping/End-Capping CRPs

entry method irradiation (nm) catalyst monomera tR (min) Mn (theor) (kDa) Mn (kDa) D̵ ref
1 CMRP 320–500 3 VA 20 5.5 6.1 1.19 90
2 CMRP 320–500 3 VA 120 24.1 17.5 1.50 90
3 ATRP 380 4 MMA 220 4.2 5.4 1.21 97
4 ATRP 380 4 MMA 220 3.1 3.3 1.23 97
5 O-ATRP white 5 MMA 90 6.6 11.1 1.07 117
6 O-ATRP white 6 MMA 120 4.9 6.6 1.18 117
7 O-ATRP white 7 MMA 90 5.0 18.9 1.10 117
8 O-ATRP white 8 MMA 120 6.5 5.8 1.19 117
9 O-ATRP 365 9 MAA 120 5.6 5.6 n/a 118
10 O-ATRP 365 9 MMA 120 5.3 4.7 2.18 118
a

MAA = methacrylic acid. See Table 1 for other details.