Skip to main content
. Author manuscript; available in PMC: 2020 Jan 15.
Published in final edited form as: Coord Chem Rev. 2017 Sep 22;379:99–120. doi: 10.1016/j.ccr.2017.09.002

Figure 23.

Figure 23

The structure of a metalloporphyrin-fullerene compound. A) Structure of triad complex composed of DP3FP and two MnII TPP. Two pyridines were grafted on the surface of fullerene. The nitrogen atoms in pyridine further coordinated with MnII TPP and formed the triad complex. B) The structure of ZnTPPH-fullerene dyad used in the photoinduced H2 evolution. Pyridine was conjugated on the surface of C60 and further occupied the axial coordination position of ZnTPPH as the ligand. This Zn-TPPH-fullerene dyad was applied for photoinduced H2 evolution. Permission obtained from Ref.[169] and [170]. Copyright by Royal Society of Chemistry and American Chemical Society.