Table 1. Polymerization conditions, bound phenolate concentrations, and TFN : CD ratio in polymer samples a .
Polymer | [Phenolate] (mmol g–1) | K2CO3 addition rate | [TFN]0 (M) | TFN : CD ratio | S BET (m2 g–1) | Yield (%) |
TFN-CDP-2 | 0.44 (+/– 0.01) | At once | 0.3 | 5.2 | 346 (+/– 113) | 64 |
TFN-CDP-3 | 0.22 (+/– 0.02) | 0.1 equiv. per h | 0.3 | 5.9 | Non-porous | 67 |
TFN-CDP-4 | 0.14 (+/– <0.01) | At once | 1.2 | 5.2 | Non-porous | 54 |
TFN-CDP-5 | 0.08 (+/– <0.01) | 0.1 equiv. per h | 1.2 | 5.9 | Non-porous | 54 |
aTFN-CDP refers to tetrafluoroterephthalonitrile-linked β-cyclodextrin polymer.