Table 1.

Summary of polymerization of DTMPC performed by various catalytic conditions. Molar ratio (%) to monomer (DTMPC, typically 100mg, 0.33 mmol). Conversion determined by GC.

Run	Catalyst		Alcohol		Temp. (°C)	Time (min)	Conversion (%)
	Catalyst	Ratio (%)	Alcohol	Ratio (%)
1	DMAP	2.5	13PDO	10	110	90	55
2	DMAP	2.5	13PDO	10	130	30	93.8
3	DMAP	2.5	13PDO	10	130	90	98.8
4	DMAP	2.5	13PDO	10	150	5	83.9
5	DMAP	2.5	13PDO	10	150	15	99.1
6	DBU	0.5	13PDO	10	110	15	92.9
7	DBU	0.5	13PDO	10	110	60	99.4
8	DBU	0.5	13PDO	10	130	15	94.9
9	DBU	0.5	13PDO	10	130	30	98.8
10	DBU	0.5	13PDO	10	150	5	95.3
11	DBU	0.5	13PDO	10	150	30	99.5
12	DBU	0.5	13PDO	1	130	30	92.5
13	DBU	0.5	13PDO	1	130	60	98.5
14	DBU	0.5	13PDO	20	130	30	99.5
15	DBU	0.5	12PDO	10	130	15	99.5
16	DBU	0.5	16HDO	10	130	30	99.4
17	TBD	0.03	13PDO	4	110	30	91.4
18	TBD	0.03	13PDO	4	110	90	96.6
19	TBD	0.03	13PDO	4	130	30	94.7
20	TBD	0.03	13PDO	4	130	60	96.1
21	TBD	0.03	13PDO	4	150	5	96.2
22	TBD	0.03	13PDO	4	150	30	99
23	TEA	2.2	13PDO	10	110	90	7.2
24	TEA	2.2	13PDO	10	130	30	53.1
25	TEA	2.2	13PDO	10	130	90	97.3
26	TEA	2.2	13PDO	10	130	30	82.7
27	TEA	2.2	13PDO	10	130	90	96.7