Table 1.
Multiple reaction monitoring data acquisition parameters for the target alkaloids.
Analyte | CAS number | Molecular weight | Precursorion (m/z) | Production (m/z) | Collision energy (eV) | Declustering potential (V) |
---|---|---|---|---|---|---|
Scopolamine | 51-34-3 | 303 | 304 | 138a | 27 | 51 |
103 | 55 | |||||
156 | 19 | |||||
L-hyoscyamine | 101-31-5 | 289 | 290 | 124a | 31 | 51 |
93 | 45 | |||||
77 | 71 | |||||
(+)-Sparteine | 90-39-1 | 234 | 235 | 98a | 49 | 86 |
70 | 71 | |||||
55 | 73 | |||||
(−)-Sparteine | 90-39-1 | 234 | 235 | 98a | 47 | 61 |
70 | 65 | |||||
55 | 77 |
Quantification ions.