Table 2.
Seasonal variation in content and chemical composition of essential oils from leaves of M. longifolia.
| Component A | Rt (min) B | KI C | % Area | |
|---|---|---|---|---|
| Spring | Winter | |||
| Monoterpene hydrocarbons | ||||
| α-pinene | 8.557 | 941 | 0.12±0.008b | 0.93±0.02a |
| camphene | 9.764 | 953 | 0.18±0.03b | 0.41±0.008a |
| β-pinene | 9.827 | 978 | 0.24±0.02b | 1.22±0.05a |
| Oxygenated monoterpenes | ||||
| 1,8 cineole | 11.492 | 1030 | 2.37±0.16b | 21.3±0.24a |
| L-menthone | 15.206 | 1152 | 4.68±0.2b | 10.66±0.1a |
| Iso-menthone | 15.429 | 1163 | 0.16±0.008b | 8.69±0.12a |
| Borneol | 15.503 | 1166 | 2.6±0.02a | 1.87±0.04b |
| Menthol | 15.801 | 1171 | 4.29±0.2a | 0b |
| Cis-isopulegone | 17.960 | 1175 | 0b | 0.86±0.04a |
| Pulegone | 18.349 | 1237 | 38.2±0.28a | 26.92±0.53b |
| Piperitone | 19.539 | 1251 | 0b | 0.82±0.1a |
| Piperitenone | 21.324 | 1340 | 1.18±0.12b | 9.62±0.2a |
| cis-Jasmone | 22.406 | 1400 | 0b | 0.45±0.02a |
| Sesquiterpene hydrocarbons | ||||
| trans-Caryophyllene | 22.949 | 1419 | 0.87±0.04b | 2.7±0.1a |
| D-germacrene | 24.046 | 1482 | 0.34±0.008a | 0b |
| gamma.-Cadinene | 25.106 | 1514 | 0b | 0.52±0.08a |
| d-Cadinene | 27.607 | 1523 | 0.4±0.006a | 0b |
| delta.-Selinene | 27.857 | 1578 | 0b | 0.30±0a |
| Oxygenated sesquiterpenes | ||||
| alpha.-Humulene | 23.659 | 1454 | 0b | 0.2±0a |
| alpha.-Cadinol | 28.196 | 1654 | 0b | 2.81±0.05a |
| Esters | ||||
| Geranyl tiglate | 29.260 | 1685 | 0b | 0.24±0.008a |
| Fatty Acids | ||||
| Palmitic acid | 34.729 | 1927 | 15.26±0.2a | 0b |
| Oleic acid | 38.002 | 2128 | 23.79±0.5a | 0b |
| Linoleic acid | 38.317 | 2173 | 3.27±0.01a | 0b |
| Total compound | 97.95 | 89.91 | ||
ACompounds listed in order of elution from a HP-5 MS column.
BRetention time (as minutes).
CK.I. Kovats Index on HP-5MS column in reference to n-alkanes.
Values in the same line with different subscript (a > b) are significantly different within season (P < 0.05).