Table 4.
Name | QC conc. | Intraday | Interday | ||||
---|---|---|---|---|---|---|---|
Concentration | RSD | Accuracy | Concentration | RSD | Accuracy | ||
(ng/mL) | (ng/mL) | (%) | (%) | (ng/mL) | (%) | (%) | |
Aconitine | 0.10 | 0.09 ± 0.01 | 6.03 | 91.18 ± 5.49 | 0.08 ± 0.01 | 8.12 | 83.09 ± 6.75 |
0.40 | 0.39 ± 0.01 | 3.31 | 98.05 ± 3.24 | 0.40 ± 0.02 | 4.06 | 100.49 ± 4.08 | |
4.00 | 4.30 ± 0.30 | 7.06 | 107.38 ± 7.58 | 4.00 ± 0.08 | 1.98 | 99.92 ± 1.98 | |
8.00 | 8.02 ± 0.36 | 4.45 | 100.25 ± 4.46 | 7.94 ± 0.19 | 2.35 | 99.28 ± 2.34 | |
| |||||||
Mesaconitine | 0.10 | 0.11 ± 0.00 | 2.20 | 111.64 ± 2.45 | 0.10 ± 0.02 | 15.88 | 100.71 ± 15.99 |
0.40 | 0.40 ± 0.01 | 3.73 | 100.26 ± 3.74 | 0.38 ± 0.03 | 7.86 | 95.08 ± 7.47 | |
4.00 | 3.96 ± 0.23 | 5.76 | 99.08 ± 5.7 | 3.98 ± 0.24 | 6.10 | 99.44 ± 6.06 | |
8.00 | 7.93 ± 0.28 | 3.57 | 99.07 ± 3.54 | 7.94 ± 0.25 | 3.15 | 99.30 ± 3.13 | |
| |||||||
Hypaconitine | 0.10 | 0.10 ± 0.01 | 5.79 | 104.52 ± 6.05 | 0.11 ± 0.00 | 3.45 | 105.48 ± 3.64 |
0.40 | 0.38 ± 0.01 | 3.39 | 95.55 ± 3.24 | 0.39 ± 0.01 | 3.82 | 97.76 ± 3.74 | |
4.00 | 4.17 ± 0.27 | 6.36 | 104.26 ± 6.63 | 4.06 ± 0.18 | 4.51 | 101.58 ± 4.58 | |
8.00 | 8.02 ± 0.36 | 4.45 | 100.25 ± 4.46 | 7.94 ± 0.19 | 2.35 | 99.28 ± 2.34 |