Figure 4.

(A,a) Synthesis of the chiral Zr-MOF, (b) post-synthetic metalation (c) asymmetric addition of aryl-boronic acid. Reproduced with permission from Falkowski et al. (2014). (B) Asymmetric alkynylzinc additions catalyzed by the chiral MOF/Ti-BINOLate catalyst. Image adjusted from Ma et al. (2010).