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Gene clusters and proposed biosynthetic pathways of duclauxins. A) Proposed biosynthetic pathways of oxaphenalenone 11 and dimerization to 1; B) LC-MS analysis of organic extracts obtained from the wild type strain and mutants (ΔduxI and ΔduxD) of T. stipitatus; C) Schematic representation of the two separate gene clusters (dux1 and dux2) from T. stipitatus.
