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Rate constants and AuNP diameters for fs experiments.
| E (mJ) | k1 (×10−6 s−1) | k2 (M−1 s−1) | Df (nm) | DTEM (nm) |
|---|---|---|---|---|
| 2.4 | 3.3 ± 2.6 | 83 ± 26 | 20 ± l | |
| 2.7 | 7.2 ± 5.5 | 104 ± 9 | 23 ± 7 | 27 ± 7 |
| 3.0 | 9.4 ± 2.5 | 171 ± 43 | 20 ± 2 | 18 ± 8 |
| 3.3 | 15 ± 10 | 242 ± 57 | 16 ± 2 | 14 ± 6 |
| 3.6 | 25 ± 16 | 358 ± 50 | 16 ± 1 |
