|
|
shell area of membranes (m2); |
|
|
total membrane surface (m2); |
|
|
total concentration (kmol·m−3); |
|
|
diffusion pre-exponential factor (m2·s−1); |
|
|
diffusivity of hydrogen in the mixture retentate side (m2·s−1); |
|
|
equivalent diameter of membranes (m); |
|
|
channel depth (m); |
|
|
activation energy for hydrogen permeation through metallic membranes (J·mol−1); |
|
|
activation energy for the diffusion of hydrogen atoms (J·mol−1); |
|
|
molar flow rate (kmol·h−1); |
|
|
mass transfer coefficient (kmol·h−1·m−2); |
|
|
overall mass transfer coefficient (kmol·h−1·m−2); |
|
|
hydrogen recovery factor; |
|
|
internal shell diameter (m); |
|
|
hydrogen flux (kmol·h−1·m−2); |
|
|
average hydrogen flux (kmol·h−1·m−2); |
|
|
mass transfer dimensional group; |
|
|
hydrogen permeance (kmol·h−1·m−1·bar−0.5); |
|
|
average hydrogen permeance (kmol·h−1·m−2·bar−0.5); |
|
|
membrane length (m); |
|
|
lower heating value (kJ/Nm3); |
|
|
natural gas (kg/h); |
|
|
number of membranes; |
|
|
outside tube diameter (m); |
|
|
outside membrane diameter (m); |
|
|
hydrogen permeability (kmol·h−1·m−1·bar−0.5); |
|
|
permeability pre-exponential factor (kmol·h−1·m−1·bar−0.5); |
|
|
tube pitch (m); |
|
|
hydrogen partial pressure on the right/left interface (bar); |
|
|
membrane internal radius (m); |
|
|
average Reynolds number; |
|
|
average velocity of the mixture, retentate side (m·s−1); |
|
|
average Schmidt number; |
|
|
channel width (m); |
|
|
hydrogen molar fraction on the retentate/lefth interface of i-esimo step; |
|
Apices and Subscripts
|
|
|
H2O, CO, CO2, CH4; |
| LI |
relative to the left-interface in the film theory; |
| m |
relative to the mixture; |
| cp |
concentration polarization; |
| ML |
logarithm mean; |
|
|
relative to the permeate; |
|
|
relative to the retentate-side; |
|
|
relative to concentration polarization; |
| M |
relative to membrane; |
|
|
relative to the right-interface in the film theory; |
|
|
relative to the shell-side; |
| t |
tube-side; |
|
Greekletter
|
| δ |
membrane thickness, (m); |
|
|
viscosity of mixture, retentate side (Pa·s); |
|
|
density of mixture, retentate side (kg·m−3); |
|
|
standard enthalpy of the surface dissociation reaction (J·mol−1·K−1); |
|
|
entropy change of the dissociation reaction (J·mol−1); |