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. 2018 Nov 14;8(4):109. doi: 10.3390/membranes8040109
as shell area of membranes (m2);
Atot total membrane surface (m2);
ctot total concentration (kmol·m−3);
D0,H diffusion pre-exponential factor (m2·s−1);
DH2,m diffusivity of hydrogen in the mixture retentate side (m2·s−1);
Deq equivalent diameter of membranes (m);
d channel depth (m);
Ea activation energy for hydrogen permeation through metallic membranes (J·mol−1);
ED activation energy for the diffusion of hydrogen atoms (J·mol−1);
F molar flow rate (kmol·h−1);
FG mass transfer coefficient (kmol·h−1·m−2);
FOG overall mass transfer coefficient (kmol·h−1·m−2);
HRF hydrogen recovery factor;
IDs internal shell diameter (m);
JH2 hydrogen flux (kmol·h−1·m−2);
J¯ average hydrogen flux (kmol·h−1·m−2);
jD mass transfer dimensional group;
KH2 hydrogen permeance (kmol·h−1·m−1·bar−0.5);
KH2¯ average hydrogen permeance (kmol·h−1·m−2·bar−0.5);
L membrane length (m);
LHV lower heating value (kJ/Nm3);
NG natural gas (kg/h);
Nm number of membranes;
ODt outside tube diameter (m);
ODM outside membrane diameter (m);
PH2 hydrogen permeability (kmol·h−1·m−1·bar−0.5);
PH20 permeability pre-exponential factor (kmol·h−1·m−1·bar−0.5);
Pt tube pitch (m);
pH2 hydrogen partial pressure on the right/left interface (bar);
r membrane internal radius (m);
Re average Reynolds number;
v average velocity of the mixture, retentate side (m·s−1);
Sc average Schmidt number;
w channel width (m);
yH2 hydrogen molar fraction on the retentate/lefth interface of i-esimo step;
Apices and Subscripts
j H2O, CO, CO2, CH4;
LI relative to the left-interface in the film theory;
m relative to the mixture;
cp concentration polarization;
ML logarithm mean;
P relative to the permeate;
R relative to the retentate-side;
R* relative to concentration polarization;
M relative to membrane;
RI relative to the right-interface in the film theory;
s relative to the shell-side;
t tube-side;
Greekletter
δ membrane thickness, (m);
μm viscosity of mixture, retentate side (Pa·s);
ρm density of mixture, retentate side (kg·m−3);
ΔSR0 standard enthalpy of the surface dissociation reaction (J·mol−1·K−1);
ΔHR0 entropy change of the dissociation reaction (J·mol−1);