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. 2018 Dec 28;14:3122–3149. doi: 10.3762/bjoc.14.292

Table 1.

Examples of metathesis reactions performed with catalysts 24a and 24b.a

entry substrate product complex loading (mol %) conversion (%)
1 Inline graphic
26 		Inline graphic
27 		GII-SIMes
24a
HGII-SIMes
24b 		0.02
0.02
0.02
0.02		 50
56
66
56
2 graphic file with name Beilstein_J_Org_Chem-14-3122-i003.jpg Inline graphic
15 		GII-SIMes
24a
HGII-SIMes
24b 		3
3
3
3		 79 (E/Z = 6:1)
72 (E/Z = 3:1)
84 (E/Z = 6:1)
76 (E/Z = 6:1)
3 Inline graphic
28 		graphic file with name Beilstein_J_Org_Chem-14-3122-i006.jpg GII-SIMes
24a
HGII-SIMes
24b 		3
3
3
3		 95 (29/30 = 1.6:1)
92 (29/30 = 1.7:1)
95 (29/30 = 1.5:1)
95 (29/30 = 2.0:1)

aReactions performed in refluxing dichloromethane [21].