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. 2018 Dec 28;14:3122–3149. doi: 10.3762/bjoc.14.292

Table 5.

Metathesis reactions of standard substrates.

entry substrate product catalyst (mol %) T (°C) t (h) isolated yield (%)
1 Inline graphic
127 		Inline graphic
128 		IndII-SIMes (2)
120 (2)
121 (2)
134 (2)
135 (2)
136 (2)
137 (2)
138 (2)
139 (2)
140 (2)
141 (2)
142 (2)		 30
30
30
40
40
50
50
50
50
50
50
50		 8
6
5
8
8
2
2
2
1.5
1.5
1.5
1.5		 96a
94a
96a
99b
99b
92c
91c
92c
89c
91c
89c
91c
2 Inline graphic
129 		Inline graphic
130 		IndII-SIMes (1)
120 (1)
121 (1)
136 (1)
137 (1)
138 (1)
139 (1)
140 (1)
141 (1)
142 (1)		 50
50
50
50
50
50
50
50
50
50		 2.5
1
2
1.25
2
1
3
3
3
3		 94a
96a
91a
87c
89c
92c
85c
94c
88c
90c
3 graphic file with name Beilstein_J_Org_Chem-14-3122-i012.jpg Inline graphic
15 		IndII-SIMes (2.5)
120 (2.5)
121 (2.5)
134 (2.5)
135 (2.5)
136 (2.5)
137 (2.5)
138 (2.5)
139 (2.5)
140 (2.5)
141 (2.5)
142 (2.5)		 30
30
30
30
30
50
50
50
50
50
50
50		 20
20
20
20
20
2
2
2
2
1.5
1.5
1.5		 74 (E/Z = 8:1)a
80 (E/Z = 9:1)a
74 (E/Z = 11:1)a
45 (E/Z = 4:1)b
86 (E/Z = 5:1)b
89 (E/Z = 7.1:1)c
76 (E/Z = 7.9:1)c
93 (E/Z = 6:1)c
74 (E/Z = 3.6:1)c
80 (E/Z = 7:1)c
81 (E/Z = 8:1)c
78 (E/Z = 6.5:1)c

aRef [43]; bRef [45]; cRef [46].