Table 1.
Solvent | 30 °C | 15 °C | ΔQEη | ΔQEη/[η] | ||
---|---|---|---|---|---|---|
[η] | k’ | [η] | k’ | |||
Water | 0.60 ± 0.03 | 2.0 ± 0.3 | - | - | - | - |
Water-3 M URE | 0.79 ± 0.03 | 0.8 ± 0.1 | - | - | - | - |
DMSO | 1.70 ± 0.10 | 0.4 ± 0.1 | 1.30 ± 0.10 | 1.1 ± 0.4 | 29.4 ± 0.9 | 17 ± 2 |
DMSO-3 M URE | 1.36 ± 0.03 | 0.44 ± 0.05 | 0.98 ± 0.05 | 0.8 ± 0.2 | 26.0 ± 0.9 | 19 ± 1 |
a) [η] is the intrinsic viscosity (dL/g); k’ is the Huggins constant; ΔQEη = Qη − Qη0 is the excess apparent activation heat of viscosity (kJ/mol); Qη and Qη0 are the apparent activation heats of viscosity for the polymer solution and solvent, respectively.