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. 2018 Oct 8;4(4):81. doi: 10.3390/gels4040081

Table 1.

Hydrodynamic parameters of PVA in different solvents a).

Solvent 30 °C 15 °C ΔQEη ΔQEη/[η]
[η] k’ [η] k’
Water 0.60 ± 0.03 2.0 ± 0.3 - - - -
Water-3 M URE 0.79 ± 0.03 0.8 ± 0.1 - - - -
DMSO 1.70 ± 0.10 0.4 ± 0.1 1.30 ± 0.10 1.1 ± 0.4 29.4 ± 0.9 17 ± 2
DMSO-3 M URE 1.36 ± 0.03 0.44 ± 0.05 0.98 ± 0.05 0.8 ± 0.2 26.0 ± 0.9 19 ± 1

a) [η] is the intrinsic viscosity (dL/g); k’ is the Huggins constant; ΔQEη = QηQη0 is the excess apparent activation heat of viscosity (kJ/mol); Qη and Qη0 are the apparent activation heats of viscosity for the polymer solution and solvent, respectively.