Table 2.
entrya | variations from above | Co(ll)+NFTPB | Co(III) BF4 | Co(III) CI |
---|---|---|---|---|
1 | LI | 79 | 55 | 44 |
2 | L2 | 82 | 56 | 42 |
3 | L2, in the glovebox | 82 | 56 | 41 |
4 | L2, 2 equiv of Mn° | 76 | 57 | |
5 | L2, NFTPB (0.3 equiv) | 70 | 53 | |
6b | dtbbpyNi(o-ToI)l (2) as | 68 | 49 |
Reactions run on 50 μmol scale. Yield determined by GC-FID with internal standard. A1-Methyl-2-(4-phenylbutan-2-yl)benzene observed in <1% overall yield (maximum yield is 10%).
1-Methyl-2-(4-phenylbutan-2-yl)benzene observed in <1% overall yield (maximum yield is 10%).