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. Author manuscript; available in PMC: 2019 Sep 26.
Published in final edited form as: J Am Chem Soc. 2018 Sep 18;140(38):12056–12068. doi: 10.1021/jacs.8b06458

Table 2.

Oxidant Not Necessary for Cobalt Turnoveraa

graphic file with name nihms-1002193-t0022.jpg
entrya variations from above Co(ll)+NFTPB Co(III) BF4 Co(III) CI
1 LI 79 55 44
2 L2 82 56 42
3 L2, in the glovebox 82 56 41
4 L2, 2 equiv of Mn° 76 57
5 L2, NFTPB (0.3 equiv) 70 53
6b dtbbpyNi(o-ToI)l (2) as 68 49
a

Reactions run on 50 μmol scale. Yield determined by GC-FID with internal standard. A1-Methyl-2-(4-phenylbutan-2-yl)benzene observed in <1% overall yield (maximum yield is 10%).

b

1-Methyl-2-(4-phenylbutan-2-yl)benzene observed in <1% overall yield (maximum yield is 10%).