Skip to main content
. 2019 Jan 11;10:167. doi: 10.1038/s41467-018-08019-7

Table 1.

Catalytic performance at 240 °C, 10 bar, H2/CO = 2, 18–30% CO conversion

CO conv., X (%) CTY (10−4 molCO. gCo−1 s−1) C1, S (%) C2–C4 olefins, S (%) C2–C4 paraffins, S (%) C5+, S (%) CO2, S (%) O/P C2–C4 α
Co 32 0.13 12 6 7 75 <2 0.8 0.69
Co3Mn1 31 0.14 11 17 10 62 <2 1.8 0.63
Co3Mn1–Na2O 20 0.09 9 14 7 42 28 1.9 0.53
Co3Mn1–Na2S 25 0.12 5 20 7 56 13 2.9 0.56
Co1Mn3 31 0.56 15 12 13 61 <2 0.9 0.67
Co1Mn3–Na2O 27 0.46 14 11 12 63 <2 0.9 0.65
Co1Mn3–Na2S 18 0.40 4 30 7 59 <3 4.2 0.53
Co1Mn3−Na2S2O3 22 0.42 7 25 12 56 <3 2.1 0.50

CO conversion (X, %), activity per gram of Co (CTY), product selectivity (S, %), The detection limit of CO2 selectivity is 0.5% yield, equivalent to 3% CO2 selectivity at 18% CO conversion.