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. 2015 Aug 28;20(9):15701–15734. doi: 10.3390/molecules200915701

Table 1.

Activation parameters derived from the Arrhenius plots without and with KI.

Without KI					With KI
Inhibitor	Conc. (ppm)	E_a (kJ·mol⁻¹)	ΔH (kJ·mol⁻¹)	ΔS (JK⁻¹·mol⁻¹)	E_a (kJ·mol⁻¹)	ΔH (kJ·mol⁻¹)	ΔS (J·K⁻¹·mol⁻¹)
Blank	-	10.55	167.00	−275.79	10.55	167.00	−275.79
Pc1	25	8.68	137.38	−283.30	8.74	138.38	−277.32
	50	7.49	118.47	−287.40	7.70	121.86	−278.44
	75	7.70	121.79	−286.77	7.21	114.17	−275.74
	100	9.09	143.91	−284.52	8.77	138.76	−276.47
Pc2	25	11.41	180.62	−274.39	11.72	185.54	−273.75
	50	11.82	186.99	−273.21	12.38	195.97	−271.76
	75	11.68	184.80	−273.76	12.14	192.07	−272.68
	100	11.58	183.24	−274.13	12.08	191.25	−272.45
Pc3	25	11.50	181.92	−274.10	11.88	187.96	−273.22
	50	11.52	182.29	−274.08	11.71	185.26	−273.74
	75	11.73	185.60	−273.60	12.05	190.72	−272.89
	100	11.10	175.71	−275.68	11.65	184.43	−273.33
Pc4	25	11.70	185.22	−273.51	12.64	200.11	−270.91
	50	12.10	191.51	−272.39	12.33	195.18	−271.94
	75	11.94	188.97	−273.02	12.18	192.70	−272.54
	100	11.47	181.56	−274.66	12.26	194.04	−272.50
nPc1	25	10.39	164.37	−277.80	10.63	168.28	−277.32
	50	10.18	161.12	−278.56	10.31	163.18	−278.44
	75	10.74	169.99	−276.90	11.21	177.47	−275.74
	100	10.57	167.30	−277.66	11.05	174.94	−276.47
nPc2	25	11.11	175.76	−275.36	11.64	184.28	−273.90
	50	11.97	189.39	−272.82	12.31	194.75	−272.02
	75	11.40	180.42	−274.72	12.03	190.42	−273.09
	100	10.34	163.60	−278.29	10.92	172.76	−276.74
nPc3	25	7.97	126.09	−285.33	8.01	126.67	−285.49
	50	8.42	133.30	−284.17	8.66	133.30	−283.52
	75	8.31	131.49	−282.54	8.39	131.49	−282.27
	100	8.89	140.76	−282.86	9.18	140.76	−282.28