. 2015 Aug 28;20(9):15701–15734. doi: 10.3390/molecules200915701

Table 2.

Thermodynamic parameters derived from the Langmuir adsorption isotherm for the studied Pcs and nPcs.

Without KI					With KI
Inhibitor	T/K	K_ads (10³ × mol⁻¹)	−ΔG°_ads (kJ∙mol⁻¹)	ΔH° (kJ∙mol⁻¹)	ΔS° (kJ∙mol⁻¹)	K_ads (10³ × mol⁻¹)	−ΔG°_ads (kJ∙mol⁻¹)	ΔH° (kJ∙mol⁻¹)	ΔS° (kJ·mol⁻¹)
Pc1	303	22.99	−18.02	18.06	0.12	69.69	−20.81	21.56	2.46
	313	76.34	−21.04	21.08		84.75	−21.31	22.08
	323	48.78	−19.91	19.95		85.47	−21.33	22.12
	333	55.25	−20.23	20.27		136.99	−22.52	23.34
	343	312.50	−24.59	24.64		180.18	−23.21	24.05
Pc2	303	15.65	−17.05	17.08	0.09	42.28	−19.55	21.07	5.00
	313	34.25	−19.02	19.05		48.19	−19.88	21.45
	323	90.09	−21.46	21.49		61.54	−20.50	22.11
	333	99.01	−21.70	21.73		76.28	−21.04	22.70
	343	51.68	−20.06	20.09		86.96	−21.37	23.08
Pc3	303	17.41	−17.32	17.34	0.09	17.41	−20.27	23.08	9.27
	313	24.54	−18.18	18.21		24.54	−20.45	23.35
	323	40.57	−19.45	19.48		40.57	−20.68	23.67
	333	86.96	−21.37	21.40		86.96	−21.08	24.17
	343	55.71	−20.25	20.28		55.71	−21.75	24.93
Pc4	303	9.38	−15.76	15.79	0.11	54.95	−20.21	25.33	16.88
	313	14.42	−16.84	16.88		58.14	−20.36	25.64
	323	35.03	−19.08	19.11		56.66	−20.29	25.74
	333	40.98	−19.48	19.51		61.35	−20.49	26.11
	343	46.84	−19.81	19.85		66.45	−20.69	26.48
nPc1	303	54.94	−20.21	20.22	0.01	65.15	−20.64	19.45	−3.95
	313	51.68	−20.06	20.06		67.11	−20.72	19.48
	323	64.72	−20.63	20.63		81.30	−21.20	19.93
	333	76.63	−21.05	21.06		101.01	−21.75	20.43
	343	59.00	−20.39	20.40		256.41	−24.10	22.74
nPc2	303	17.41	−17.32	17.35	0.10	93.90	−21.56	28.91	24.25
	313	19.36	−17.59	17.62		134.23	−22.46	30.05
	323	53.33	−20.14	20.17		82.99	−21.25	29.08
	333	70.92	−20.86	20.89		92.59	−21.53	29.60
	343	66.89	−20.71	20.74		96.62	−21.64	29.95
nPc3	303	47.28	−19.84	19.86	0.09	108.70	−21.93	28.72	22.41
	313	51.95	−20.07	20.10		128.21	−22.35	29.36
	323	20.41	−17.72	17.75		99.50	−21.71	28.95
	333	116.96	−22.12	22.15		116.96	−22.12	29.58
	343	173.91	−23.12	23.15		111.11	−21.99	29.67