Table 1. Summary of equilibrium, exchange constants, and thermochemical data at 20 °C (293 K) in DCM.
K
eq
|
ΔH (kcal mol–1) | ΔS (eu) | τ f (ps) | E a (kcal mol–1) | ||
IR | K 10 | 0.35 (0.03) | 0.84 (0.08) | 0.6 (0.4) | 4.3 (1.5) | 2.2 (0.2) |
K 02 | 2.9 (0.2) | –2.18 (0.06) | –5.3 (0.3) | 6.3 (1.6) | 2.4 (0.1) | |
K 12 | 1.0 (0.1) | –1.3 (0.1) | –4.8 (0.5) | 8.6 (2.0) | 2.6 (0.1) | |
UV-vis | K 12 | 1.4 (0.3) | –1.3 (0.1) | –3.4 (0.2) | — | — |