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. 2018 Oct 8;10(1):113–117. doi: 10.1039/c8sc03258k

Table 1. Summary of equilibrium, exchange constants, and thermochemical data at 20 °C (293 K) in DCM.

K eq
ΔH (kcal mol–1) ΔS (eu) τ f (ps) E a (kcal mol–1)
IR K 10 0.35 (0.03) 0.84 (0.08) 0.6 (0.4) 4.3 (1.5) 2.2 (0.2)
K 02 2.9 (0.2) –2.18 (0.06) –5.3 (0.3) 6.3 (1.6) 2.4 (0.1)
K 12 1.0 (0.1) –1.3 (0.1) –4.8 (0.5) 8.6 (2.0) 2.6 (0.1)
UV-vis K 12 1.4 (0.3) –1.3 (0.1) –3.4 (0.2)