Table 2. Chemical shifts of H_β and H_meso in CDCl₃.

Complex		δHβ a (ppm)	δHmeso a (ppm)
[IrIII(ttp)Cl(CO)]		8.96	—
[IrIII(tmp)Cl(CO)]		8.66	—
[IrIII(oep)Cl(CO)]		—	10.31
[IrIII(F20tpp)Cl(CO)]		9.01	—
[IrIII(tmp)(IMe)Cl]	1a	8.32	—
[IrIII(tmp)(BIMe)Cl]	1b	8.36	—
[IrIII(F20tpp)(IMe)Cl]	1c	8.58	—
[IrIII(F20tpp)(BIMe)Cl]	1d	8.62	—
[IrIII(ttp)(IMe)2]+	2a	8.61	—
[IrIII(ttp)(BIMe)2]+	2b	8.69	—
[IrIII(oep)(IMe)2]+	2c	—	9.39
[IrIII(oep)(BIMe)2]+	2d	—	9.45
[IrIII(oep)(IiPr)2]+	2e	—	9.40
[IrIII(F20tpp)(IMe)2]+ b	2f	8.70	—
[IrIII(oep)(CNPhOMe)2]+	3	—	10.31
[IrIII(oep)(py)2]+	4	—	10.21

^aValues reported with reference to δH(Si(CH₃)₄) = 0 ppm.

^bMeasured in CD₂Cl₂.