Table 4. UV-visible absorption and emission data of [Ir^III(por)Cl(CO)] and 1–4.

Complex	UV-vis absorption data a		Emission data a
	λ max nm–1 (log ε)		Solution at 298 K
			λ max/nm (τ/μs)	Φ em [×10–2]
[IrIII(ttp)Cl(CO)]		309 (4.50), 422 (5.58), 533 (4.41), 567 (3.89)	724 (47.2), 808 (sh)	0.16
[IrIII(tmp)Cl(CO)]		311 (4.43), 422 (5.58), 533 (4.42), 564 (3.60)	721 (77.2), 800 (sh)	0.22
[IrIII(oep)Cl(CO)]		342 (4.44), 403 (5.38), 518 (4.30), 549 (4.62)	666 (83.3), 722 (sh)	5.03
[IrIII(F20tpp)Cl(CO)]		329 (4.40), 414 (5.42), 526 (4.45), 557 (3.94)	676 (101.0), 746 (sh)	2.92
[IrIII(tmp)(IMe)Cl]	1a	345 (sh) (4.29), 368 (4.56), 431 (5.18), 542 (4.06), 593 (3.40)	773 (1.8)	0.05
[IrIII(tmp)(BIMe)Cl]	1b	301 (4.55), 367 (4.61), 431 (5.23), 545 (4.13), 592 (3.92)	775 (2.3)	0.06
[IrIII(F20tpp)(IMe)Cl]	1c	346 (sh) (4.44), 371 (4.62), 426 (5.10), 533 (4.12)	— b	— b
[IrIII(F20tpp)(BIMe)Cl]	1d	296 (4.41), 346 (sh) (4.39), 369 (4.55), 426 (5.10), 535 (4.12)	729 (1.7), 811 (sh)	0.29
[IrIII(ttp)(IMe)2]+	2a	374 (4.76), 438 (5.12), 547 (3.87), 620 (3.82) (br) c	Nonemissive	—
[IrIII(ttp)(BIMe)2]+	2b	297 (4.63), 372 (4.63), 437 (4.99), 564 (3.85) (br) d , 611 (3.87) (br) c	Nonemissive	—
[IrIII(oep)(IMe)2]+	2c	351 (sh) (4.52), 372 (4.86), 429 (4.89), 532 (4.10), 556 (4.01)	701 (2.7), 766 (sh)	0.41
[IrIII(oep)(BIMe)2]+	2d	297 (4.42), 373, (4.76), 428 (4.82), 533 (4.03), 557 (3.95)	701 (3.6), 765 (sh)	0.66
[IrIII(oep)(IiPr)2]+	2e	353 (sh) (4.49), 375 (4.82), 432 (4.82), 537 (4.09), 560 (4.02)	701 (1.9), 763 (sh)	0.03
[IrIII(F20tpp)(IMe)2]+	2f d	355 (sh) (4.63), 374 (4.89), 418 (sh) (4.72), 440 (5.00), 537 (4.13)	754 (0.5), 829 (sh)	0.08
[IrIII(oep)(CNPhOMe)2]+	3	266 (4.70), 344(sh) (4.36), 395 (5.20), 515 (4.17), 547 (4.50)	663 (124.7), 717(sh)	6.40
[IrIII(oep)(py)2]+	4	388 (5.25), 507 (4.11), 539 (4.54)	651(55.2), 711(sh)	12.30

^aMeasurements were performed in degassed CHCl₃.

^bComplex 1d was unstable for emission measurements.

^cBroad absorption band spans from ca. 510 to 670 nm.

^dMeasurements were performed in degassed CH₂Cl₂.