Table 1. Binding parameters for hosts 1tBu and 2CF3 with the anions used in this study a .
Host | Solvent | HSe– |
Br– |
HS– |
Cl– |
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K a (M–1) | ΔG (kcal mol–1) | K a (M–1) | ΔG (kcal mol–1) | K a (M–1) | ΔG (kcal mol–1) | K a (M–1) | ΔG (kcal mol–1) | ||
1tBu | 10% DMSO-d6/CD3CN | 460 ± 50 | –3.63 ± 0.06 | 110 ± 20 | –2.79 ± 0.09 | 3600 ± 500 | –4.85 ± 0.09 | 1700 ± 200 | –4.41 ± 0.06 |
2CF3 | CD3CN | 290 ± 50 | –3.35 ± 0.10 | 67 ± 7 | –2.49 ± 0.06 | 840 ± 80 | –3.93 ± 0.06 | 430 ± 50 | –3.59 ± 0.07 |
aThe minimum error is assumed to be 10% in cases where the standard deviation is less than 10%.