Skip to main content
. 2018 Nov 19;10(1):67–72. doi: 10.1039/c8sc03968b

Table 1. Binding parameters for hosts 1tBu and 2CF3 with the anions used in this study a .

Host Solvent HSe
Br
HS
Cl
K a (M–1) ΔG (kcal mol–1) K a (M–1) ΔG (kcal mol–1) K a (M–1) ΔG (kcal mol–1) K a (M–1) ΔG (kcal mol–1)
1tBu 10% DMSO-d6/CD3CN 460 ± 50 –3.63 ± 0.06 110 ± 20 –2.79 ± 0.09 3600 ± 500 –4.85 ± 0.09 1700 ± 200 –4.41 ± 0.06
2CF3 CD3CN 290 ± 50 –3.35 ± 0.10 67 ± 7 –2.49 ± 0.06 840 ± 80 –3.93 ± 0.06 430 ± 50 –3.59 ± 0.07

aThe minimum error is assumed to be 10% in cases where the standard deviation is less than 10%.