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. 2018 Nov 28;48(1):45–49. doi: 10.1039/c8dt04563a

Table 2. Click reactions of UiO-67 and UiO-67 modified by post synthetic exchange to include L-N3 and L-C Created by potrace 1.16, written by Peter Selinger 2001-2019 C appended linkers. Clicked products detected by 1H NMR of post-reaction digested MOF.

(A) Single click reactions
Linkers CuI? Reactants Observed clicked products Yield
Native only Y graphic file with name c8dt04563a-u1.jpg None
L-N3 Y None
L-N3 N graphic file with name c8dt04563a-u2.jpg None
L-N3 Y graphic file with name c8dt04563a-u3.jpg graphic file with name c8dt04563a-u4.jpg 46%
L-C Created by potrace 1.16, written by Peter Selinger 2001-2019 C Y None
L-C Created by potrace 1.16, written by Peter Selinger 2001-2019 C N graphic file with name c8dt04563a-u5.jpg None
L-C Created by potrace 1.16, written by Peter Selinger 2001-2019 C Y graphic file with name c8dt04563a-u6.jpg graphic file with name c8dt04563a-u7.jpg 59%
L-N3 & L-C Created by potrace 1.16, written by Peter Selinger 2001-2019 C Y None
(B) Double click reaction
Linkers Step Reactants Observed clicked products Yield
L-N3 & L-C Created by potrace 1.16, written by Peter Selinger 2001-2019 C (1) graphic file with name c8dt04563a-u8.jpg graphic file with name c8dt04563a-u9.jpg 50%
(2) graphic file with name c8dt04563a-u10.jpg 50%