Table 1.
Samples | Φ (°C/min) | t1/2 (min) | G (min−1) | n | lnkt | lnkc | k c |
---|---|---|---|---|---|---|---|
PP/WF0 | 5 | 0.66 | 1.52 | 2.76 | 0.75 | 0.15 | 1.16 |
10 | 0.36 | 2.78 | 2.89 | 2.60 | 0.26 | 1.30 | |
20 | 0.14 | 7.14 | 2.95 | 5.40 | 0.27 | 1.31 | |
30 | 0.07 | 14.29 | 3.02 | 7.50 | 0.25 | 1.28 | |
PP/WF10 | 5 | 0.74 | 1.35 | 2.93 | 0.50 | 0.10 | 1.11 |
10 | 0.38 | 2.63 | 2.89 | 2.40 | 0.24 | 1.27 | |
20 | 0.21 | 4.76 | 3.09 | 4.40 | 0.22 | 1.25 | |
30 | 0.11 | 9.09 | 3.02 | 6.30 | 0.21 | 1.23 | |
PP/WF20 | 5 | 0.76 | 1.32 | 2.76 | 0.40 | 0.08 | 1.08 |
10 | 0.44 | 2.27 | 2.91 | 2.00 | 0.20 | 1.22 | |
20 | 0.26 | 3.85 | 2.95 | 3.60 | 0.18 | 1.20 | |
30 | 0.13 | 7.69 | 3.02 | 5.70 | 0.19 | 1.21 | |
PP/WF30 | 5 | 0.78 | 1.28 | 2.72 | 0.30 | 0.06 | 1.06 |
10 | 0.50 | 2.00 | 2.85 | 1.60 | 0.16 | 1.17 | |
20 | 0.30 | 3.33 | 2.99 | 3.20 | 0.16 | 1.17 | |
30 | 0.17 | 5.88 | 3.09 | 5.20 | 0.14 | 1.15 | |
PP/WF40 | 5 | 0.81 | 1.23 | 2.75 | 0.20 | 0.04 | 1.04 |
10 | 0.52 | 1.92 | 2.87 | 1.50 | 0.15 | 1.16 | |
20 | 0.36 | 2.78 | 2.91 | 2.60 | 0.13 | 1.14 | |
30 | 0.25 | 4.00 | 2.90 | 3.60 | 0.12 | 1.13 |
Φ: cooling rate, t1/2: crystallization half-time, G: crystallization rate, n: Avrami exponent, lnkc: logarithm of the modified kinetics constant, kc: modified crystallization kinetic constant.