Table 3.
13C (150 MHz) NMR data of compound 1a and compounds 2–5 b (δ in ppm).
No | 1 | 2 | 3 | 4 | 5 | No | 1 | 2 | 3 | 4 | 5 |
---|---|---|---|---|---|---|---|---|---|---|---|
1 | 97.1 | 97. 8 | 97. 4 | 97. 9 | 97.4 | 4′ | 70.2 | 71. 5 | 71. 5 | 71. 6 | 71.5 |
3 | 152.3 | 153. 2 | 154.2 | 153. 3 | 154.2 | 5′ | 76.1 | 78. 4 | 78. 5 | 78. 4 | 78.5 |
4 | 104.7 | 111.7 | 109.5 | 111.7 | 109.5 | 6′ | 65.3 | 62.8 | 62.8 | 62.8 | 62.8 |
5 | 22.0 | 29. 4 | 39.6 | 29. 3 | 39.6 | 11-OMe | - | 51.7 | 51.8 | 51.7 | 51.7 |
6 | 29.5 | 33. 2 | 133. 5 | 33. 1 | 133.4 | 1′′ | 62.3 | - | 173.5 | 66.3 | 173.6 |
7 | 100.1 | 104.4 | 126.6 | 104.0 | 126.6 | 2′′ | 15.2 | - | 38.6 | 33.7 | 38.6 |
8 | 131.6 | 135. 8 | 135. 8 | 135. 8 | 135.8 | 3′′ | - | - | 61.8 | 20.5 | 65.6 |
9 | 42.4 | 45.3 | 46.3 | 45.4 | 46.3 | 4′′ | - | - | 14.5 | 14.3 | 31.8 |
10 | 121.2 | 119. 8 | 118. 8 | 119. 8 | 118.8 | 5′′ | - | - | - | - | 20.2 |
11 | 169.1 | 169. 1 | 168. 8 | 169. 1 | 168.7 | 6′′ | - | - | - | - | 14.1 |
1′ | 98.8 | 100.1 | 100.2 | 100.1 | 100.2 | 7-OMea | - | 53.9 | - | 53.8 | - |
2′ | 73.5 | 74. 6 | 74. 7 | 74. 7 | 74.8 | 7-OMeb | - | 52.5 | - | - | - |
3′ | 75.8 | 78. 0 | 78. 0 | 78. 1 | 78.0 |
a NMR data were obtained in chloroform-d. b Data were measured in methanol-d4.