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. Author manuscript; available in PMC: 2019 Jan 19.
Published in final edited form as: Chem Rev. 2018 Jun 22;118(14):6573–6655. doi: 10.1021/acs.chemrev.8b00031

Figure 102.

Figure 102.

C-C bond cleavage by the P450 enzyme Fma (A. fumigatus af510), with a proposed ferric peroxide reaction in the upper pathway and a Compund I mechanism in the lower part.62,349