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. Author manuscript; available in PMC: 2019 Jan 19.
Published in final edited form as: Chem Rev. 2018 Jun 22;118(14):6573–6655. doi: 10.1021/acs.chemrev.8b00031

Figure 42.

Figure 42.

Glutamate mutase and cobalamin chemistry.165167 (A) Overall reaction; (B) general cobalamin 1,2-migration mechanism. In Part A the carbon atoms are labeled (*, #) to indicate the rearrangement.